Source: Biogas & Electric LLC submitted to NRP
NOVEL APPROACH TO NOX REDUCTION IN BIOGAS ENGINE EXHAUST FROM ANAEROBIC DIGESTION FACILITIES AT DAIRY FARMS.
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0226128
Grant No.
2011-33610-30776
Cumulative Award Amt.
(N/A)
Proposal No.
2011-02367
Multistate No.
(N/A)
Project Start Date
Sep 1, 2011
Project End Date
Aug 31, 2013
Grant Year
2011
Program Code
[8.11]- Animal Waste Management
Recipient Organization
Biogas & Electric LLC
4186 Sorrento Valley Blvd, Suite M
San Diego,CA 92121
Performing Department
(N/A)
Non Technical Summary
Biogas & Electric LLC proposes a novel low cost approach to NOx and SO2 removal through a combination of extended absorption and selective non-catalytic reduction. If efficacy in the proposed NOx removal process can be shown, the new method will be adopted by all proposed manure based anaerobic digestion projects in California, and shortly thereafter adopted by many other manure based anaerobic digestion projects across the globe.
Animal Health Component
25%
Research Effort Categories
Basic
(N/A)
Applied
25%
Developmental
75%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
1410499202025%
1415370200025%
4033499202025%
5113499202025%
Goals / Objectives
The goal of the Phase II research is to build upon the Phase I findings by establishing scalability, reliability and cost effectiveness of the novel NOx and SO2 reduction method for biogas engines. To achieve this goal, the following objectives will be met. A. Conduct pilot studies identifying the optimum system dimensions, pressure, liquid waste handling system, anti-foaming structure, and exhaust cooling and handling system. B. Design and construct a commercial scale apparatus and implement the project at a dairy based anaerobic digester. C. Document construction and operational savings associated with the apparatus. D. Analyze and document the chemical analysis of the waste fluid both before and after interaction with engine exhaust within system. NOx and SO2 levels before and after the system will be measured and compared to regulatory mandated levels.
Project Methods
Perform a survey of processes used in industry and documented in literature. Investigate and inspect existing implementations and interview system designers where possible. Test selected techniques in Phase I Proof-of-Concept Vehicle as necessary. This will primarily target techniques that are shown in literature but have not been demonstrated at any significant scale. Create detailed system models for candidates selected. Analytical modeling will focus on thermodynamic parameters (flow rates, temperatures, and pressures) and processes (interfacing and mixing of fluids, heat exchange, et cetera.) Combine requirements for systems resulting from into a superset system that can be reconfigured to test each option. Develop the main test plan that will provide operational data to either validate or invalidate the target processes under investigation. The specific system performance requirements and instrumentation strategy will be generated to meet the process specifications and to enable running the system at the extents defined by the plan. Identify primary responsible parties for design and fabrication of subsystems. Release responsible parties to proceed. Identify interface requirements and development hardware to meet requirements. Identify control system requirements and specify system to meet requirements. Specify supporting hardware and plan necessary to test and buyoff completed system after assembly and prior to delivery at final site location. Perform overall system assembly and system integration. Break down and package system for shipment to jobsite. Reassemble the system at test site. Integrate with site utility and process supplies. Checkout system and equipment with the test plan. Check system for integration with biogas engine and site utility and process supplies. Release for inspection. Train facility personnel and site host how to operate the systems use emergency disconnects. Perform system burn-in test: Run at boundaries of operating parameters for a sufficient period to demonstrate system reliability. This is supervised operation. Collect and reduce system operational data. Prepare summary report for program. Determine operational costs by calculating the electrical needs of each component. The electrical needs of each component can be determined by recording the Voltage and Amperes of each electrical component. The resulting annual kWh will then be multiplied by the dairy's purchase price of electricity to determine the estimated annual electrical cost of each component. Each component's cost will then be summed together to determine the estimated annual operating cost of the complete system. Use a TESTO 350 XL gas analyzer to analyze NOx and SO2 levels before and after the system and compare to the regulatory mandated limits.

Progress 09/01/11 to 08/31/13

Outputs
Target Audience: We have met and spokenwith a number of municipal wastewater treatment plant and agriculteralanaerobic digestor opporators and project develpoersat meetings andwere selected to present atconferencessuch as the2013BioCycle West Coast Conference, 2013 California Water Environment Association Conference, Orange County/Islesponsored TAG meeting. We have also met with representitives from Waste Management, Inc., Caterpillar, and GE.We have received requests for proposals from biogas project developers such as Harvest Power, Anaergia, and Ag Power Group. Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided? Both Michael Matelich and Seth Burns developed professionally through interaction withdairy managementand technology providers in developing a successful demonstration project. Additionally, interaction with potential customers and presenting to various trade groups has provided addtional professional development for both Seth Burns and Michael Matelich. How have the results been disseminated to communities of interest? We maintain an informative webpage at www.biogasandelectric.com. We wrote and widelydistributed a whitepaperoutliningthe progress and results we obtained during the project period at our dairy-based demonstration project. We have attended a number of industry conferences as invitedspeakers and given presentations covering our process and results. We have also maintained an informative booth at several of these conferences. What do you plan to do during the next reporting period to accomplish the goals? Nothing Reported

Impacts
What was accomplished under these goals? Goals A & B The full scale NOxRx® demonstration facility was installed at a 3,500 head flushed lane California based dairy. The site was equipped with a stirred, covered lagoon type anaerobic digester of approximately 30 million gallons. A biogas stream of 75 - 150 scfm is produced by the digester. The biogaswas passed through a coiled-loop chiller to condense and remove water prior to combustion. The H2S concentration varies between 6,000 ppm and 15,000 ppm. No specific sulfide removal was employed prior to combustion. The full biogas stream is used to power a 300 kW Guascor lean burn CHP biogas engine.Biogas & Electricdesigned and installed a solution to treat the exhaust from the biogas engine. The results from Phase II are encouraging. Using untreated wastewater fromthis dairy based anaerobic digester, Biogas & Electric was able to reduce NOx to levels that meet the California Air Resource Board 2007 standard of 0.07 lbs. per MW-hr. or 2-3 ppm. This NOx level is better than Selective Catalytic Reduction (SCR) the current Best Available Control Technology (BACT) which is technically capable of reducing NOx levels to the 9-11 ppm level. Goal C The following table is an estimate of energy consumption used by the NOxRx® process: Voltage Amperage Watts Kw Oxidant #1 220 7 1540 1.5 Oxidant #2 220 7 1540 1.5 Exhaust fan – 3 HP 460 5 2300 2.3 (Drain) Sump Pump – 5 HP 460 7 3220 3.2 Supply Pump – 5 HP 460 7 3220 3.2 11.8 Table 3 - Energy Consumption of NOxRx® The energy demands for a NOxRx® solution will be dependent largely on how far wastewater needs to be pumped to and from the project, which varies from project to project. If electricity is $.07 per Kilowatt Hour, the operating cost of NOxRx® for the Bullfrog Farms installation can be calculated as follows: 11.8 Kw x 24 hours/day x $.07/Kw = $19.86/day or $7,248/year. The current leading technology is SCR or Selective Catalytic Reduction, requires H2S removal from the biogas prior to combustion. Bullfrog Farms has looked into H2S reduction solutions, and has determined that an H2S reduction system is prohibitively expensive for their operation. A cost comparison between SCR and NOxRx® can be summarized below: Selective Catalytic Reduction (SCR) NOxRx® CAPEX: $ 100,000 CAPEX: $ 250,000 H2S Removal System: $ 300,000 H2S Removal System: $ - OPEX: $ 25,000 OPEX: $ 7,250 Interest Rate: 6% Interest Rate: 6% Project Term (years): 10 Project Term (years): 10 Net Present Value: ($561,361) Net Present Value: ($289,210) Year Cash Outlay Year Cash Outlay 1 $ (425,000) 1 $ (257,250) 2 $ (25,000) 2 $ (7,250) 3 $ (25,000) 3 $ (7,250) 4 $ (25,000) 4 $ (7,250) 5 $ (25,000) 5 $ (7,250) 6 $ (25,000) 6 $ (7,250) 7 $ (25,000) 7 $ (7,250) 8 $ (25,000) 8 $ (7,250) 9 $ (25,000) 9 $ (7,250) 10 $ (25,000) 10 $ (7,250) Table 4 - Cost Comparison of SCR vs. NOxRx® Furthermore, many biogas project developers in the San Joaquin Valley have had difficulty with SCR systems reliably meeting the existing NOx regulations of 9-11 ppm, indicating that the technical limit of SCR is 9-11 ppm. NOxRx® has demonstrated reproducible operation for extended periods of time at 2 ppm NOx, indicating a technical limit of at least 2 ppm. Thus, NOxRx® is more economical, and it also more effective than SCR, the current Best Available Control Technology in many air districts across the nation. Goal D Host test site requirements and infrastructure limitations precluded continuous, unattended operation of the system, therefore this task could not be accomplished as written. However, effluent samples were obtained and analyzed after prolonged periods of attended operation (hours). Changes were detected in pH and ORP consistent with the amount of SO2 absorbed. No measurable differences were detected in otherwater chemistry (ie analysis for nitrate; only difference was pH and Sulfate).

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