Source: Precision Combustion, Inc. submitted to NRP
ETHYLENE CONTROL FOR PRODUCE
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
1028393
Grant No.
2022-70031-36943
Cumulative Award Amt.
$181,495.00
Proposal No.
2022-00781
Multistate No.
(N/A)
Project Start Date
Jul 1, 2022
Project End Date
Feb 28, 2025
Grant Year
2022
Program Code
[8.5]- Food Science & Nutrition
Recipient Organization
Precision Combustion, Inc.
410 Sackett Point Road
North Haven,CT 06473
Performing Department
(N/A)
Non Technical Summary
We will study the use of our compact high efficiency photocatalytic oxidation reactor for control of ethylene, and other volatile organic compounds, that are naturally generated by produce during transportation and controlled atmosphere storage. Coupled with a dedicated ethylene sensor, our system will enable improved storage life and freshness of a variety of tree fruits and vegetable crops while reducing spoilage. In Phase I, we will focus on apple storage, developing proof of concept for our system, working at the environmental conditions prevalent in local apple storage operations. Phase I field testing in local commercial apple facilities and outreach, including food distribution centers, mixed produce refrigeration, and long distance and international refrigerated shipping, will lead to Phase II pre-commercial field testing for a variety of applications beyond apples.We expect our system to integrate with existing ventilation equipment and have a cost payback of about one year due to simplicity of operation, high intrinsic efficiency and no need for maintenance or replacement parts. Current methods of ethylene control involve the use of disposable sorbents or other materials that represent a labor and environmental burden to operators. Additionally, our approach will reduce the number of air changes needed to maintain optimum produce storage conditions, as ethylene will be controlled by our reactor rather than through energy-intensive atmosphere exchange potentially with specialty gases.
Animal Health Component
40%
Research Effort Categories
Basic
20%
Applied
40%
Developmental
40%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
50311192020100%
Goals / Objectives
We will study the use of our compact high efficiency reactor for control of ethylene, and other volatile organic compounds, that are naturally generated by produce during transportation and controlled atmosphere storage. Coupled with a dedicated sensor, our system will enable improved storage life and freshness of a variety of tree fruits and vegetable crops while reducing spoilage. In Phase I, we will focus on apple storage, developing proof of concept for our system, working at the environmental conditions prevalent in local apple storage operations. Phase I field testing in local commercial apple facilities and outreach, including food distribution centers, mixed produce refrigeration, and long distance and international refrigerated shipping, will lead to Phase II pre-commercial field testing for a variety of applications beyond apples.We expect our system to integrate with existing ventilation equipment and have a cost payback of about one year due to simplicity of operation, high intrinsic efficiency and no need for maintenance or replacement parts. Current methods of ethylene control involve the use of disposable sorbents or other materials that represent a labor and environmental burden to operators. Additionally, our approach will reduce the number of air changes needed to maintain optimum produce storage conditions, as ethylene will be controlled by our reactor rather than through energy-intensive atmosphere exchange potentially with specialty gases.Benefits include:Sensor-responsive ethylene control and removal for controlled ripening/preservation of flavor and potential extension of the high-quality apple storage period,Avoidance of costly chemical treatments for storage,Reduced cold storage stress (e.g. scald, by limiting ethylene and hormones in post-cold ripening)Possible reduced cold chain costs, e.g. potential for less reliance on inerts by limiting ethyleneUse for produce with weaker response to chemicals or cold storage/inerting, e.g. peaches, plums. Stone fruits may enjoy longer high freshness storage capability.A potentially enlarged organic sector due to longer high freshness storage life.Specific goals and metrics:A) Achieve greater than 50% single-pass ethylene conversion in controlled atmosphere (CA) storage conditions (2.5% O2, 2.5% CO2, bal. N2, ~90% RH, ~33 °F) for 0.5 to 5 ppm C2H4.B) Optimize reactor operationsto maximize conversion efficiency.C) Demonstrate no detectable byproducts (including CO, CH2O and CH2O2 with state-of-the-art on- or off-line detectors at the optimum conditions.D) Confirm performance of the above metrics in a commercial CA facility or equivalent research facility.E) Conduct outreach to establish further development for apple CA storage, at least one other tree fruit, and at least one other crop
Project Methods
Methods to be used are primarily laboratory experiments with related analysis and modeling, hardware design, build and testing, as well as field trials. Specifically, we intend to perform the following:Conduct initial project overview with partner organizations and collaborators to review goals and metricsBench scale testing to confirm performance of reactor at conditions specific to apple storage environment, as stated by our partner organizations. This work will lead to optimization of both reactor hardware and internals as well as reactor operating conditions.We will design test hardware for use off-site, either at local apple storage facilities or at a University Agricultural Extension Service. Using a combination of optimum processing conditions and reactor design parameters determined previously, we will develop a first-order kinetic rate model that will allow for determination of rate-limiting steps and calculation of reactor size. Short term durability testing, in the range of 100 hours, will be completed. This will permit a preliminary design to be completed in which space velocity, conversions, volume, and weight can be specified. We will also program a PLC for on/off operation, interfaced to take input from our portable ethylene meter for use in controlling the reactor in order to reach a specific ethylene concentration.Develop specifications for a full-scale unit or units for use in an average sized controlled atmosphere room, which will be confirmed in follow-on Phase II work. The outcome will be a design package in which size, weight, power, cost, performance, and durability will be specified, with unknowns or aspects for improvements identified. Selected full scale components will be sourced. The performance data will be used to inform and build a techno-economic model, with the goal of providing a complete cost and benefit picture of using our reactor.Working with our partners, we will determine the cost benefits of our system to various concerns in the value chain, including growers, transporters, storage facilities, wholesale and retail operations, as well as to consumers. Costs and benefits of our approach will be ranked against published studies of other ethylene mitigation strategies or with estimated performance.This information will then be used to prepare a summary of the project and a white paper, to aid in outreach to a range of concerns in produce storage and transportation. Our business development team will focus on furthering relationships with our letter-of-support providers, other concerns we have held discussion during the course of preparing this proposal, and in developing new relationships. The goal will be to identify at least one tree-fruit (other than apple) and one vegetable or mixed produce facility for Phase II demonstrations.

Progress 07/01/23 to 02/29/24

Outputs
Target Audience:Target audience - the entire true fruit post-harvest value chain, including cold transportation, cold storage, delivery to and from storage facilities and potentially commercial and consumer point-of-sale, including mixed fruit / vegetable refrigerated grocery store and similar. Our Phase I will be focused on apple cold storage facilities, we have identified several local growers in Connecticut that will work with us to demonstrate our ethylene control technology. For Phase II, we have identified a potential partner for assessing our device in long-distance cold transportation in 40' trailers. Changes/Problems:Set out in the Phase I proposal, we planned to evaluate our ethylene control device at a New England-based University and at local growers. Due to delays in contracting, project funds were not available until 8/30/2023. During this time delay, the University apple test facility was shuttered and remains unavailable indefinitely. Additionally, we are not able to enter local growers' facilities during peak fall/winter harvest times. Consequently, to conduct field testing for proof of concept of our approach we require access to apple research and grower facilities during late winter / spring time frames. What opportunities for training and professional development has the project provided? Nothing Reported How have the results been disseminated to communities of interest? Nothing Reported What do you plan to do during the next reporting period to accomplish the goals? End March, 2024: Contact local growers to arrange details on field testing. Finish build-out of in-house testing equipment. Design field portable test device. End May, 2024 Identify university or Ag-extension apple research facility, determine appropriateness for cooperative work. Firm commitments for testing at local grower facilities. Build and test field portable device. Complete initial phase of testing on in-house device. Determine best metrics for apple evaluation and quality. End of August, 2024: Complete in-house performance and process studies Complete local grower and/or apple research facility field evaluations End of December, 2024: Complete cost analysis studies, evaluate requirements for larger scale and commercial size devices. Complete partnering remaining commercialization activities. End of project, February 28, 2025: Finish remaining evaluations and tasks Submit final report

Impacts
What was accomplished under these goals? Accomplishments by goal: A) we have identified and sourced both lab and transportable equipment for measuring ethylene and evaluating performance of our ethylene control device. E) TABA has been completed. Below lists the highlights of the TABA report, which can be made available to NIFA on request. ?Commercial ethylene control products exist in the market, namely the pre-cold-storage chemical treatments PCI is intent to replace. Charmingly, the market players are small, specialty companies, not the well-known agrochemical behemoths. There are a couple of top players, but the industry is still fragmented. Within the commercial ethylene absorber market, the environment control system dominates the type-segment as of year 2021, these systems would be pricey compared with sachets. Nine companies were identified as manufacturing mechanical control systems for ethylene. A number of the companies also offer an HVAC module for ethylene extraction. Background - Ethylene Sensitive Crops: Over two billion tons of fruits and vegetables are produced annually, yet almost half of fruits and vegetables are lost or wasted with 22% lost in the supply chain post-harvest to distribution. A respiratory increase in a fleshy fruit -- which is preceded, or accompanied, by a rise in ethylene --is called a "climacteric." A key difference between climacteric and non-climacteric fleshy fruits (particularly for commercial production) is that climacteric fruits continue to ripen following their harvest, whereas non-climacteric fruits and vegetables do not. There are marked differences in the development of climacteric and non-climacteric fruits. Climacteric fruit are those who's ripening can still be achieved even if the fruit has been harvested at the end of their growth period (prior to ripening on the parent plant). Examples of climacteric fruits include apples, bananas, melons, mangos, apricots, tomatoes, avocados as well as most stone fruits. The accumulation of starch over the initial stages of climacteric fruit development may be a key issue, as starch can be converted to sugars after harvest. Cut flowers are known to produce ethylene gas. When flowers are cut from the plant, they can continue to produce ethylene, which can affect their vase life and overall quality. Non-climacteric fruits ripen without ethylene and respiration bursts, the ripening process is slower, and for the most part they will not be able to ripen if the fruit is not attached to the parent plant. Non-climacteric fruits include citrus fruits, cranberries, grapes, raspberries, pineapple, and strawberries. That said, non-climacteric melons and apricots do exist. Grapes and strawberries harbor several active ethylene receptors, although they are generally not considered ethylene sensitive. Cabbage and brussels sprouts will turn yellow or crack and start to grow, carrots develop a bitter flavor due to ethylene-induced isocoumarin production and cucumbers deteriorate quicker. Snap beans and peas in a pod are sensitive to ethylene, but lima beans are not. Seeds may be affected. Early potatoes are not sensitive to ethylene, but late potatoes and sweet potatoes are. Lettuce is extremely sensitive to ethylene gas. Fruits and flowers that produce ethylene and those that are sensitive to ethylene make up a large subset of perishable fruits, vegetables, and flowers. Ethylene sensitivity drives transportation and logistics choices. In Phase I, the primary focus will be on apples. Apples have a very long storage life and are ethylene sensitive. They are climacteric fruits and produce ethylene during storage. Apples are stored at high humidity and below 40 oF. Maintaining proper moisture levels helps slow down the natural ripening process and enzymatic activities that contribute to deterioration. PCI will establish a proof of concept through testing under environmental conditions typical of local apple storage facilities. Additionally, PCI will engage with food distribution centers that deal with mixed produce refrigeration, as well as long-distance and international refrigerated shipping. Phase will add pre-commercial field tests extending beyond apples. The benefits offered by this approach includes a reduction in the need for or the complete elimination of pre-cold-storage chemical treatments. For apples, the ethylene absorber market leader is 1-Methylcyclopropane. So called MCP-1 is conventionally applied to mitigate apple ethylene respiration and curb superficial scald formation. The project's success would empower growers to transition towards cultivating more organic and healthier apples. This shift would result in lower fruit handling costs due to reduced ventilation requirements, as well as diminished damage and losses. PCI's projections indicate that similar enhancements can be expected for other tree fruits that are less suited for cold storage, such as plums and peaches. Furthermore, the benefits extend to vegetables, cut flowers, and scenarios where mixed produce needs to be stored within refrigerated spaces. Given that all other necessary conditions are met, the utilization of our system could offer growers the opportunity to venture into organic produce cultivation more readily. This could potentially lead to significantly increased profits by avoiding the need for chemical ethylene control. Commercial Potential: The total addressable market for the primary application of this technology comes from published reports by industry analysts. The estimate is global market size for PCI and for all competitors. The demand for organic fruits and vegetables has grown in recent years as consumers have become more aware of the potential health and environmental benefits of organic farming practices. Organic products are often perceived as healthier and more environmentally friendly than conventionally grown products. Globally, the Organic Fruits and Vegetables Market was valued at $39.5 Billion in 2021 and is projected to reach USD 68.5 Billion by 2028. Organic Fruits and Vegetables Industry is expected to increase significantly compared to the forecast period's market, with a CAGR of 8.2%.The US holds roughly 41% of that market, followed by Europe. Organic vegetables are 61% of that market. Fresh Organic Apple Market: According to US Apple, the apple is the #1 fruit eaten in the US. All 50 states grow apples, although only 32 grow them commercially. In the U.S. 67% of the apple crop is grown for fresh consumption. Globally, Fresh Apple Market size is estimated at $99 billion in 2023, and is expected to reach $109 billion by 2028, growing at a CAGR of 2%. Other studies predict a 4% CAGR. The higher-income groups in these regions are even willing to pay additional amounts, with an aim to safeguard their health conditions. While US acreage and production of apples have declined in recent years, consumer demand has spurred a fast-growing organic apple sector. According to Ag Marketing Resource Center, in 2021, apples managed under certified organic farming systems accounted for about 7% of total US apple acreage. The retail prices for fresh organic apples was, on average, 40% higher than for conventional fresh apples. Controlling Superficial Scald: Superficial scald is a physiological disorder causing brown or black patches on fruit skin that appears during or after storage on apples and pears. Fruit with scald is also called russetted fruit. At least partial control of the disorder can be obtained from application of antioxidants, especially the commonly used diphenylamine (DPA), as well as low oxygen storage; scald development is assumed to be an oxidative process.

Publications


    Progress 07/01/22 to 06/30/23

    Outputs
    Target Audience:Local apple / fruit growers and state / univerisity agricultural extension offices Changes/Problems:Project initiation was delayed due to adminstrative issues which have now been resolved as of August 31, 2023. What opportunities for training and professional development has the project provided? Nothing Reported How have the results been disseminated to communities of interest? Nothing Reported What do you plan to do during the next reporting period to accomplish the goals?We will initiate and complete the proposed work plan.

    Impacts
    What was accomplished under these goals? Work did not commence during the reporting period.

    Publications