Source: UNIVERSITY OF ILLINOIS submitted to NRP
NUTRIENT SEPARATIONS, WATER REMOVAL AND ENERGY EFFICIENCY IN BIOPROCESSING
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
1022217
Grant No.
(N/A)
Cumulative Award Amt.
(N/A)
Proposal No.
(N/A)
Multistate No.
(N/A)
Project Start Date
Feb 24, 2020
Project End Date
Sep 30, 2024
Grant Year
(N/A)
Program Code
[(N/A)]- (N/A)
Recipient Organization
UNIVERSITY OF ILLINOIS
2001 S. Lincoln Ave.
URBANA,IL 61801
Performing Department
Agri Engineering
Non Technical Summary
Many processes using agricultural commodities and biomass as inputs use water intensively. As a result, process streams carry nutrients consisting of proteins, carbohydrates, lipids, bioactive compounds, vitamins and minerals. While containing potentially valuable components, these process streams are large in volume and are dilute. These conditions create challenging recovery and low or negative economic value of recovered solids. For example, thin stillage from ethanol production is produced at a rate of 7 L per 1 L ethanol and has 5% total solids for an industry producing about 60 billion L ethanol per year. Other process streams in industry include steepwater and process water from corn wet milling.Conventional drying processes are inherently energy intensive because of the phase change with evaporation of water and other solvents. Impact of drying methods on coproduct nutritive value largely are undetermined. For the case of thin stillage, water is removed by evaporation to concentrate solids from 5 to 35%. Thin stillage is usually mixed and dried with other process solids to form distillers dried grains with solubles (DDGS), which has value similar to that of corn.As the biofuels industry grows, sustainable use of water and recovery of nutrients will become increasingly important. In the US, more than 200 biorefineries are in operation; nearly all of these plants use corn, an important crop for Midwestern states. Plant capacities range from 40 to 120 million gallons ethanol per year (mmgy). With a thin stillage recycle rate of 35%, a 40 mmgy plant will remove 140 mmgy water using evaporation. As the use of biomass to produce ethanol becomes commercially viable, new process streams will result, increasing the need to sustainably recover water and nutrients.Fuel ethanol plants use multiple effect evaporators to concentrate thin stillage. Evaporators must be cleaned at intervals of 1 to 2 weeks, resulting in economic and capacity losses at the plant. Labor and chemical costs are incurred to clean the evaporators, a plant must reduce processing or shut down entirely during cleaning, and additional evaporator capacity must be installed if the plant wants to continue operating during cleaning. Cleaning procedures add water to the process; water and cleaning chemicals must be routed appropriately, either for reuse or disposal. When processing difficulties arise, such as during poor fermentation or incomplete liquefaction, evaporators can be expected to foul more rapidly.Separation processes upstream from the evaporator affect its efficiency. Process designs to produce valuable coproducts also affect process efficiency and long term sustainability. As the biorefinery industry grows and matures, long term economic operations will become increasingly important and impact the communities where they are located. Developing new uses and, more importantly, higher value for coproduct solids in process streams is needed to retain bioprocessor competitiveness and can be accomplished through new process designs, incorporation of new technology or combinations of both.
Animal Health Component
50%
Research Effort Categories
Basic
50%
Applied
50%
Developmental
(N/A)
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
40224102020100%
Goals / Objectives
1.Develop processes that enhance the value of agricultural materials, especially grain processes, such as membrane separations.2.Use emerging technologies or technologies from other industries in bioprocesses to dewater, dry or convert solids into higher valued coproducts.3.Gain understanding of mechanisms that hinder or enhance separations of nutrients in process streams, including fouling of heat transfer surfaces.
Project Methods
Various process systems and unit operations will be studied in an effort to improve the economic and nutritive value of process streams. Methods to convert agricultural materials, such as grains, into food and industrial products, and recover, dewater, and dry solids from these processes will be investigated. Development of new processing systems will be emphasized.Membrane filtration technology will be applied to grain and biofuels processes to conserve water and recover nutrients, thus reducing flows to waste treatment facilities. Microfiltration and ultrafiltration unit operations, focusing on commercially available membrane materials and using a range of pore sizes, will be applied to process streams such as thin stillage and the solids separations studied (Objective 1).It is expected that membrane filtration will improve compositions of retained solids as well as reduce the amount of water to be removed by thermal methods such as evaporation (Objective 2). Information on improved coproduct composition (e.g., improved phosphorus content) will be collected with processing information (e.g., water removal and recycle possibilities) that could be used in other research. Based on previous work (Agbisit et al 2003, Arora et al 2009, 2011a,b, Wilkins et al 2006a,b) the role of membrane filtration in reducing heat transfer fouling will be investigated further and coupled with recent expertise in using our fouling test apparatus and model fluids.Membrane filtration, due to its selective separations, can be incorporated in experimental designs that will increase our understanding of the causes of heat transfer fouling, leading to reduced evaporator fouling (Objective 3). By use of model process streams, insights can be gained regarding causes of accelerated fouling (Challa et al 2017, Rausch et al 2013, You et al 2019) and the desired effect from membrane separations. Although not a direct outcome of this work, it is anticipated that the information gathered during the project could be used to develop economic simulations and cost analyses for improved bioprocesses (e.g., Arora et al 2011).

Progress 02/24/20 to 09/30/20

Outputs
Target Audience:Biorefinery personnel, chemical and enzyme suppliers and equipment providers all have an interest in understanding and reducing the fouling of evaporators, or improvements to processes that mitigate fouling overall. Commodity organizations that represent feedstock suppliers have interests in process developments and fouling causes since these will improve demand for their commodities. Changes/Problems:Despite the COVIDpandemic, we can have students safely work in our laboratory, using appropriate PPE, sanitation and distancing protocols. However, the pandemic has kept many students away from campus, limiting opportunities to have them work on research projects. This has slowed our research this year, but we are hopeful that the new vaccine will alleviate this problem in the latter half of 2021. What opportunities for training and professional development has the project provided?1. In spring of 2020, despite the COVID-19 pandemic, we were able to have an undergraduate safely complete an independent research project and create a draft report. Equipment issues were identified and corrected as part of the training project. 2. In fall of 2020, with the pandemic ongoing, another undergraduate student completed an independent research project that made initial investigation into using the apparatus to measure effectiveness of cleaning methods. How have the results been disseminated to communities of interest?The data collected over this year will eventually be disseminated to our target audiences. More data and analysis are needed, however. What do you plan to do during the next reporting period to accomplish the goals?We are developing relationships with enzyme companies to gauge their interest in collaborating with us on fouling research. Their enzyme products can be used to more effectively clean fouling deposits, without use of chemicals that may increase disposal costs. They have indicated interest in measuring cleaning effectiveness.

Impacts
What was accomplished under these goals? Biorefineries are subject to widely varying market conditions. To withstand changes in the market values of their products, biorefineries must work to keep their operating costs as low as possible. Process modifications and development of new processes are key to long term sustainability. Fouling of heat transfer equipment, such as evaporators, is a recurring problem that reduces profits. Our work seeks to develop methods that avoid fouling and provide information to clean equipment efficiently. This year, we made progress towards our goals in the following ways: 1. Our equipment was updated and tested to make sure it would provide reliable data. This was achieved through an undergraduate research project. 2. Initial work investigated using our fouling experimental apparatus to measure the effectiveness of various cleaning strategies. Initial data were collected: It appears the apparatus can be used to study parameters used for chemical and enzyme cleaning methodologies.

Publications

  • Type: Journal Articles Status: Published Year Published: 2020 Citation: You, J., Johnston, D.B., Dien, B.S., Singh, V., Engeseth, N.J., Tumbleson, M.E. and Rausch, K.D. 2020. Effects of nitrogenous substances on heat transfer fouling using model thin stillage fluids. Food Bioprod. Proc. (119):125-132.
  • Type: Journal Articles Status: Published Year Published: 2021 Citation: Zheng, Y., Johnston, D.B., Engeseth, N.J., Singh, V., Tumbleson, M.E. and Rausch, K.D. 2020. Effects of compositional variables on fouling behavior of thin stillage. Food Bioprod. Proc. (125)141-148.