Source: TEXAS A&M UNIVERSITY submitted to NRP
SUSTAINABLE BIOPROCESSES FOR RECOVERY OF HIGH-VALUE PROTEIN PRODUCTS FROM PLANTS AND MICROALGAE
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
1018439
Grant No.
(N/A)
Cumulative Award Amt.
(N/A)
Proposal No.
(N/A)
Multistate No.
(N/A)
Project Start Date
Dec 26, 2018
Project End Date
Dec 26, 2023
Grant Year
(N/A)
Program Code
[(N/A)]- (N/A)
Recipient Organization
TEXAS A&M UNIVERSITY
750 AGRONOMY RD STE 2701
COLLEGE STATION,TX 77843-0001
Performing Department
Biological & Agricultural Engineering
Non Technical Summary
It has been 25 years since the first heterologous protein was expressed in tobacco followed by an antibody expression in microalgae (Fisher et al., 2003; Nikolov and Woodard 2004; Woodard et al., 2009; Mayfield et al., 2003, Rasala et al. 2010). Compared to microbial, animal, and mammalian cell cultures, plants and microalgae are attractive systems for production of native and recombinant proteins because they do not propagate human pathogens and are inexpensive to cultivate (Buyel, 2015). However, lower than expected protein expression levels have been a major obstacle for the development of economical bioprocesses. In addition, the low protein accumulation levels have hindered the design of novel protein extraction and recovery methods from plant or algal biomass. The recent technology advancements such as direct gene transcription in cell organelles suited for protein accumulation, targeting proteins to subcellular locations for optimal and stable accumulation as well as transient expression have opened a new chapter in the exploration of plants and algal systems for protein production. These latter developments have solved the accumulation challenge and reignited industry interest in alternative, cost-competitive plant - and algae-derived protein products. The goal of this project is to develop bioprocessing solutions that would make for protein production from plants and microalgae economically viable.A similar bioprocess interest surge is been observed (i.e., development of effective bioprocessing methods) with native (non-recombinant) microalgal protein products due to the need to fulfill the anticipated dietary protein demand in the coming decades. The current world population of 7.3 billion has a protein consumption demand of 202 million tons (MT), which is projected to increase to 360-1250 MT by 2050 (Henchion et al., 2017; Ritala et al., 2017). These projections underscore the need to fill the protein gap for the growing population's needs with an additional protein source. High-protein content (50%), nutritional properties, and low allergenicity (Becker, 2007a; Ritala et al., 2017) compare microalgae favorably to common protein sources such as soy (37%), milk (26%), meat (43%), and yeast (39%) (Barka & Blecker, 2016; Becker, 2004; Wells et al., 2017). In addition to nutritional quality attributes, current lifestyle trends, such as the increased consumption of health-promoting, vegan and sustainable food products, and diets that support sporting activities for health preservation (Bomgardner, 2015) have brought microalgae at the forefront of non-animal protein sources. Although the demand for non-animal sourced protein products has increased in the past 5 years, development of scalable protein extraction and recovery methods from algal biomass has not materialized. Consequently, suboptimal microalgal bioprocessing typically results in suboptimal product yield and high product cost. For example, current microalgal bioprocessing costs account for almost 60% of total product costs, while the industry benchmark for other protein feedstock (soybeans, peas, milk) is less than 30% (Lam et al., 2018). To match this industry benchmark, multiple, expensive, and time-consuming unit operations, which are currently used to produce different protein products from microalgae, have to be replaced, modified and/or optimized (Lam et al., 2018).Regardless of intended application (i.e., food or therapeutic protein products), the common principle to reduce protein manufacturing cost is to design a high-yielding and simple downstream process (Nikolov and Woodard, 2004; Buyel, 2014). The current downstream processing of recombinant proteins from mammalian and microbial systems relies on selective and rather costly bioseparations methods that typically contribute to 90% of the manufacturing cost (Evangelista et al., 1998). Bioprocessing cost of food protein isolates and hydrolysates are much lower, about 30% of the total manufacturing cost, but their economic value is also more than two orders of magnitude lower than that of therapeutic proteins. For the latter protein products process yields are important and so is the opportunity to capture by-product(s) value of algal and plant biomasses such as omega fatty acids, antioxidants, plant oils, and polysaccharides. Therefore, to reap the benefits of low-cost plant and algal biomass production one needs to develop bioprocess technologies that are less expensive than those currently used for microbial and mammalian cell culture platforms. Several reviews of protein production platforms (Nikolov et al., 2009; Rasala et al., 2010; Wilken and Nikolov, 2012, Soto-Sierra et al., 2018) indicate that no single plant or algal platform is capable of delivering desired products at a cost comparative to current protein production systems (crops, cell cultures, and bacteria). Thus, process development goals for a specific product would vary consistent with product application and market size. For plant-derived therapeutic products, such as vaccines and antibodies, novel and less expensive methods for protein purification are desirable. In the case of industrial and food proteins from microalgae, efficient fractionation of plant tissue and extracts to capture high-value co-products (antioxidants, polysaccharides, pigments and other bioactive molecules) is critical.In summary, the current world population of 7.3 billion has a protein consumption demand of 202 million tons (MT), which is projected to increase to 360-1250 MT by 2050. These projections underscore the need to fill the protein gap for the growing population's needs with an additional protein source.To reap the benefits of low-cost plant and algal biomass production we haveto havebioprocess technologies at our disposal that are less expensive than those are currently used for microbial and mammalian cell culture platforms. The goal of this project is to develop bioprocessing solutions that would make for protein production from plants and microalgae economically viable.
Animal Health Component
50%
Research Effort Categories
Basic
0%
Applied
50%
Developmental
50%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
50121502020100%
Knowledge Area
501 - New and Improved Food Processing Technologies;

Subject Of Investigation
2150 - Aquatic plants;

Field Of Science
2020 - Engineering;
Goals / Objectives
The overall objective of this project is to design economical processes for protein recovery from plants and microalgae. The specific project objectives are to:Investigate and correlate properties of plant and algal source materials relevant to product extractability and stability.Identify process conditions that are essential for achieving optimal protein purification.Use high-throughput process development methods and process modeling to synthesize optimal, scalable, and economical bioprocess.
Project Methods
Objective 1. Investigate and correlate properties of plant and algal source materials relevant to product extractability and stability.To understand how to improve bioprocess efficiency, we will analyze first the effect of plant and microalgal extracts on the quality and stability of the target protein product. Because extract complexity depends on biomass (cell) structure and process conditions, high-throughput screening and optimization of extraction parameters will be performed. The selected plant and algal biomass will be processed and extracted under different conditions (pH, temperature, mixing time, ionic strength, biomass-to-water ratio, etc.). Extracted native proteins, carbohydrates, phenolics, and proteases will be identified and quantified. To assess target protein stability and interactions with the native extract components that could alter its activity/quality, extracts from non-transgenic (native) tissue will be spiked with a purified protein of interest from a different source or with a protein of similar properties (size, pI, activity, etc.). Spiking experiments conducted with a well-characterized protein molecule will eliminate complications such as incomplete in vivo protein processing and presence of degradation products of unknown origin often found in plant or algal extracts.Objective 2. Identify processing conditions that are essential for achieving an optimal protein purification.The purpose of this objective is to determine: 1) plant- or algae-derived impurities in the clarified extracts that may interfere with protein purification; and 2) process conditions (i.e., pH, salt, ionic strength, temperature, etc.) that can be manipulated to reduce the negative impact of impurities on downstream processing. The working hypothesis of this objective is that understanding the complexity of clarified plant or algae extracts and identifying physico-chemical properties of the mixture will enable the development of strategies for systematic removal of impurities and design of efficient (high-yielding) bioseparation methods.To assess the effect of impurities and their potential interference during downstream processing, native plant or microalga extracts, characterized in Objective 1, will be processed and fractionated by membrane filtration and adsorption chromatography - the two most common unit operations that are currently employed in the biotech industry. Extract molecules and processing conditions that result in fouling of ultrafiltration membranes and/or chromatographic resins will be identified first. Then, biomass tissue pre-treatment and extraction methods will be investigated and optimized to reduce the membrane and/or resin fouling. When prudent, other unit operations such as salt and isoelectric precipitation and two-phase aqueous extraction would be included as pretreatment or primary purification methods. High-throughput process development methods will be used to determine adsorption kinetics and dynamic binding capacity of chromatography resins (Nfor et al. 2010; Bergander et al. 2008). For industrial and food protein products, less expensive methods such as membrane filtration and protein precipitation will be screened as ultimate protein purification tools. The experimental design to achieve this objective will be flexible and open-ended.Objective 3. Use high-throughput process development methods and process modeling to synthesize optimal, scalable, and economical bioprocess.The data compiled from Objective 2 will be used to assemble bioprocess train alternatives (Hanke and Ottens, 2014). Feasibility and potential process bottlenecks of assembled downstream trains will be examined using an expert simulation software (SuperPro Designer, Intelligen, 2000). The most plausible and economical process designs will be experimentally tested at the lab and then scaled-up. The process simulation analysis will allow us to decide what unit operations, extract properties, and process conditions may need additional re-evaluation. Another task within this objective is to develop heuristic design rules-of-thumb ("bioprocessing philosophy") for translating collected data into product-tailored bioprocessing strategies (Hanke and Ottens, 2014). The data for the development of heuristics will be collected in a database with inputs that will include regulatory constraints, physico-chemical properties of critical extract components, market requirements, and process economics. Relevant and reliable published literature data will also be included in the database. The ultimate goal is to develop a prototype expert modeling system for bioseparations development of high-value bioproducts (Hanke and Ottens, 2014; Steffens et al., 2000).

Progress 10/01/19 to 09/30/20

Outputs
Target Audience:Graduate and undergraduate students at Texas A&M who enrolled in"Fundamentals in Bioseparations", and "Bioprocesses and Separations in Biotechnology" courses. Undergraduate students who were interested and participatedin algae bioprocessing research in my lab. Graduate internes enrolled in the Master of Biotechnology Program and undergraduateinterns from the Biological and Ag Engineering Department. Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided?The project trained three graduate students and providedresearchexperience for two biologicaland ag.engineering undergraduate students. How have the results been disseminated to communities of interest?The results of this research have been presented at one scientific meeting, discussed in class lectures and communicated to a broader audience i.e. parents and perspective undergraduate students visiting the BAEN department and my laboratory. What do you plan to do during the next reporting period to accomplish the goals?Future work will include 1) redesigning the enzyme deactivation method to prevent lysine degradation; 2) evaluation of hydrolysate temperature and pH stability for applications in specialized protein drinks and 3) process modeling to determine economic feasibility of manufacturing algal protein hydrolysates from lipid depleted biomass.

Impacts
What was accomplished under these goals? Impact The projected dietary protein need in the coming decades is formidable. The dietary protein demand has been predicted to increase to a level as high as 1250 metric tons. To meet the projected increase in protein demand and provide adequate food security this project aims to develop economical and sustainable algal bioprocessing technologies to provide a source of high quality and nutritious proteins. Microalgae are a promising alternative source of dietary protein products with well-established nutritional and functional properties and low allergenicity. Due to its abundance and sustainable production potential, microalgae are considered a long-term alternative to animal-sourced protein. However, production of dietary protein from algal biomass is not trivial. The cost of algae cultivation, harvesting, and dewatering is prohibitively high for manufacturing protein products (concentrates, isolates, and hydrolysates) on a par with current plant and animas sourced proteins. The ultimate goal of the project is to develop ground-breaking innovations in extraction and fractionation technologies to capture the full potential of microalgae-derived protein products. This report addresses project Objectives #1 and #2. Objective #3 will be addressed next year. 1. Understanding the impact of biomass pre-processing on enzyme-assisted protein extraction and hydrolysis The objectives of this study was 1) to compare protein hydrolysis of three differently processed algal biomass samples, Lipid-Extracted Algae (LEA) and lysed LEA and Protein Concentrate (ProtConc), and 2) to determine the impact of starting biomass prep on protein extraction yield. The analysis of processing steps required to produce LEA, lysed LEA and ProtConc revealed that production of protein hydrolysates from LEA or lysed LEA would be simpler and potentially less expensive than from protein concentrates (ProtConc). The process of producing protein concentrate, in addition to cell lysis by homogenization, involves lysate clarification and protein precipitation. Therefore, the production of protein-rich LEA or lysed LEA material does not require protein extraction and precipitation as ProtConc process does and should theoretically results cost savings. On the other hand, the potential challenge associated with the direct application of hydrolyzing enzymes (proteases) to lipid-extracted algal biomass material is achieving greater than 50% protein extraction yield. The reason for reported lower yields is not clear, but potential causes may include non-productive binding of the proteolytic enzyme to cell wall and debris, internal accumulation of hydrolyzed protein when using LEA, and restricted penetration and access of the proteolytic enzymes to host proteins located in the algal chloroplast. To compare the maximum achievable protein yield using the three different algal biomass starting material, LEA, lysed LEA, and ProtConc suspensions were incubated with a commercial protease preparation (Alcalase) using a constant enzyme dosage [NZL1]of 3.5 ml Acalase per 100 g protein (3.5% v/w). To accesses the effectiveness of enzymatic hydrolysis, both kinetics of hydrolysis and released protein yield were measured. The kinetics of protein hydrolysis were measured via the degree of hydrolysis, and protein yields were estimated by measuring the protein concentration of centrifuged supernatant after 2, 3, and 4 h of hydrolysis. The data showed that the protein hydrolysis rate and extraction yield of lysed LEA (disrupted cells) and ProtConc concentrate were not significantly different. These results indicate that the presence of cell debris in the LEA lysate did not impart a significant change on the enzymatic reaction rate. The latter implies that cell debris did interfere by some type of non-productive interaction with Alcalase enzyme. And, protein hydrolysate yields using lysed LEA and ProtConc reached 75% value already after 2 hours incubation. 2. Improving purity and quality of protein hydrolysates The obective of this investigation was to increase the purity of hydrolysates. Isoelectric precipitation followed by centrifugation, depth filtration and ion exchange (IEX) treatment of clarified supernatant were evaluated. At the end of lysed LEA hydrolysis, the released soluble peptides remained in the slurry together with insoluble debris, cells, and unhydrolyzed protein. An isoelectric precipitation (pH 4.5) step was used to precipitate unhydrolyzed protein, which was then removed together with cell debris by centrifugation and polished be a depth filtration. The removal of unhydrolyzed protein reduced the chlorophyll content in the supernatant. After the centrifugation and depth filtration of hydrolyzed protein slurry, the cumulative protein recovery was 64% and purity - 63%. The ion exchange treatment of the protein product increased to protein purity from 64 to 72%. The increase of protein purity was primarily due to the removal of the salt generated during acidification of hydrolysate. To determine if pH 9.5 hydrolysis impacted the nutritive value of the native algal protein, the amino acid profile of the protein hydrolysate was compared to that of native microalgae protein. Protein hydrolysates and native algae protein extracts had comparable amino acid profile and essential amino acid distribution. A slight decrease of the lysine content (from 5.6% to 4.8%) of the hydrolysates compared to native algal protein extracts was observed. The amount of lysine in the hydrolysates, was significantly lower compared to whey and soy protein isolates. Significant results and findings Our findings demonstrate that: 1) mechanical cell disruption prior to enzymatic hydrolysis is required to overcome the recalcitrant microalgae biomass and reach greater than 70% yield; 2) there is no need to remove cell debris from the cell lysate prior to enzymatic hydrolysis because the presence of cell debris does impede the progress (kinetics) and extend of enzymatic hydrolysis; and 3) the proposed integrated extraction and fractionation process can deliver 75% pure protein hydrolysates with a minimal discoloration from residual chlorophyll.

Publications

  • Type: Journal Articles Status: Published Year Published: 2020 Citation: Damaj, M.B., Jifon, J. L., Woodard, S. L., Vargas-Bautista. Barros, G, Molina, J. White, S. G., Damaj, B.B., Nikolov, Z. L., Mandadi, K.K. 2020. Unprecedented enhancement of recombinant protein production in sugarcane culms using a combinatorial promoter stacking system, Scientific Reports, 10: 13713. doi.org/10.1038/s41598-020-70530-z.
  • Type: Journal Articles Status: Published Year Published: 2020 Citation: Soto-Sierra, L. Kulkarni, S. Woodard, S. Nikolov, Z. L. 2020. Processing of permeabilized Chlorella vulgaris biomass into lutein and protein-rich products. J. Applied Phycology, 32: 1697-1707. doi 10.1007/s10811-020-02055-x.
  • Type: Journal Articles Status: Published Year Published: 2019 Citation: Guo, S., Ravi, A, Mayfield, S, Nikolov, Z. L. 2019. Exploring the separation power of mixed-modal resins for purification of recombinant osteopontin from clarified E. coli lysates. Biotechnol. Progress, 35:1-12.
  • Type: Journal Articles Status: Published Year Published: 2018 Citation: Soto-Sierra, L. Stoykova, P. Nikolov, Z. L. 2018. Extraction and fractionation of microalgae-based products. Algal Research, 36:175-192


Progress 12/26/18 to 09/30/19

Outputs
Target Audience:Graduate and undergraduate students at Texas A&M who took courses on Introduction to Biochemical Engineering and Bioprocesses and Separations in Biotechnology. Undergraduate students who participated in algae bioprocessing research in my lab. Undergraduate interns from the department and Texas A&M Master in Biotechnology Program. Participants of Biological Engineering Annual Conference, and international audience that attended the 2nd International Congress of Food Technology in Serbia and the 6th International Congress of Science and Technology of Biofuels, in Cartagena, Columbia. Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided?This project trained threegraduate students in biological and agricultural engineering, one undergraduate student, and a graduate studentin MS Biotechnology program. Graduate students had opportunity to present their research achievements at a professional conference. How have the results been disseminated to communities of interest?Results have been presented at three scientific meetings, discussed in class lectures and communicated to a broader audience i.e. parents and perspective undergraduate students visiting the BAEN department and my lab. What do you plan to do during the next reporting period to accomplish the goals?Experiments will continue as described in the objectives.

Impacts
What was accomplished under these goals? The progress report addresses project objectives #1 and #3: 1. Investigate and correlate properties of raw material (algal biomass) relevant to product extractability and stability. Chlorella vulgaris is one the several microalgae species known to be a good source of proteins and pigments such as lutein and chlorophylls, which offer several health and nutraceutical benefits. The aims of this objective were 1) to evaluate the effectiveness of pulsed electric field (PEF) on cell permeabilization and subsequent ethanol extraction of lutein and chlorophyll from freshly harvested Chlorella vulgaris and 2) determine the effect of PEF permeabilization method on protein losses during lutein extraction. PEF permeabilization method significantly increased extraction yields of lutein (~2-3 fold) and chlorophyll (~10 fold) compared to extraction of freshly harvested cells without any pretreatment. To better understand the effect of PEF treatment on the kinetics of lutein and chlorophyll extraction, we have examined their release from permeabilized cells into the ethanol phase for a period of 120 min. The lutein extraction rate from PEF-permeabilized biomass with ethanol was fast in the first 10 min and then was significantly reduced past the 45 min time point. The control sampleneeded 60 min contact time to get maximum amount of lutein. The results confirmed that the PEF-treatment promoted permeabilization of the cell membrane, which enhanced the transport of smaller molecules such as lutein and chlorophyll across the cell membrane. A slower chlorophyll extraction kinetics compared to lutein for either treated or not PEF- treated biomass suggests that cell permeabilization may not be the sole reason for the observed difference. The thirtyfold lower solubility of the chlorophyll in ethanol (5-10 mg/L) compared to lutein (300 mg/L) and chlorophyll association with the protein complex of photosystems I and II could be factors affecting the slower release and lower than expected chlorophyll extraction (51 % of total) from permeabilized cells. The effect of ethanol alone on membrane permeabilization and extraction of the two pigments is demonstrated by examining the respective controls in Figure 2. For example, the majority of lutein (>90%) could be extracted in three stages by providing fresh ethanol at each stage to control (not PEF treated) biomass. Exposing the chlorella biomass from the first stage to fresh ethanol in the following two stages allowed maintaining sufficient concentration difference to drive the diffusion of solubilized lutein out of the cell. The chlorophyll extraction did have a similar extraction pattern as lutein, but different endpoints. In the first stage, a very small fraction (< 5%) was extracted, followed by a higher amount (9%) in the second stage, and about 7% in the third. The results of this comparison show that ethanol penetrates the cell membrane to reach lutein and chlorophyll in the chloroplast, but only lutein can be extracted without PEF-pretreatment. The difference in extracted chlorophyll between treated and untreated samples suggests that ethanol diffusion alone into the chloroplast is not sufficient for releasing chlorophyll molecules from the light harvesting complexes embedded in the thylakoid membrane. Therefore, application of PEF or another cell disruptive method to break chlorophyll-protein complexes associated with thylakoid membrane would be necessary if chlorophyll and/or chloroplast protein are desired products. 2. Use high-throughput process development methods and process modeling to synthesize optimal, scalable, and economical bioprocess. This objective addresses the economic feasibility of lutein extraction and integrated lutein and protein co-extraction technologies.Experimental data presented in the previous sections indicated that the main advantage of the PEF treatment is the reduction in processing time, i.e., lutein extraction could be performed in a single stage with less than 1h of contact time with ethanol and less than 15 % protein loss to the ethanol extract. While implementation of the PEF-treatment reduces downstream costs by? almost 40%, the total (upstream plus downstream) direct production cost of $3.0 g-1 lutein is still high given the current selling price of lutein-containing nutraceutical products from $1.5 to $3.5 g-1-lutein. Considering the current high biomass production cost, there is little incentive for further improvement of downstream processing efficiency because the latter contributes to less than 40% (20-40%) of lutein production cost. However, it is quite clear that the reduction of the upstream cost i.e. biomass cost, should be a target for delivering cost-competitive nutraceutical products from microalgae.Lowering the cost of algal biomass is also an important target for developing protein products from microalgae. Therefore, combining the production of both lutein and protein from the same starting algal biomass might be a reasonable strategy of distributing the cost burden of the starting material over the two co-products. The use of lutein-depleted microalgae biomass has a lower market value ($0.2-0.4 kg-1) compared to whole algae ($10 kg-1). The process cost scenario presented in Figure 6 and section 3.4.1 $0.4 kg-1 suggests that the production cost of protein concentrates of $4.2 kg-1 would fall within the bulk price range of protein concentrates produced from whey, soybeans, and peas ($3-5 kg-1). The current bottleneck of algal-derived protein concentrates is the marginal product purity of 60-65% that can be achieved with thedescribed process. At this purity and direct production cost of $4.2 kg-1, algal protein concentrates would be difficult to market against the established soy and whey concentrates and isolates. To achieve greater profit margins, further process development effort would be needed to increase the extracted protein purity to 90%. Thus, 1.5-fold increase in protein purity would be needed for algal protein products to compete with current soy and whey protein isolates (> 90% protein content), which have a threefold higher value than concentrates. Although the integrated lutein and protein co-production process requires improvements and optimization, we demonstrated that the utilization of previously extracted biomass could increase economic feasibility for developing protein products from microalgae.

Publications

  • Type: Journal Articles Status: Published Year Published: 2018 Citation: Soto-Sierra, L. Stoykova, P. Nikolov, Z. L. (2018). Extraction and fractionation of microalgae-based products. Algal Research, 36:175-192.
  • Type: Journal Articles Status: Published Year Published: 2018 Citation: Guo, S., Ravi, A, Mayfield, S, Nikolov, Z. L. Exploring the separation power of mixed-modal resins for purification of recombinant osteopontin from clarified E. coli lysates. 2019. Biotechnol. Progress, 35, 1-12.
  • Type: Journal Articles Status: Published Year Published: 2018 Citation: Kulkarni, S. and Nikolov, Z. L. 2018. Process for selective extraction of pigments and functional proteins from Chlorella vulgaris. Algal Research, 35: 185-193.
  • Type: Journal Articles Status: Published Year Published: 2018 Citation: Marrone, B., Lacey, R, Nikolov, Z. L., et al., 2018. Review of the harvesting and extraction program within the National Alliance for Advanced Biofuels and Bioproducts, Algal Research, 33: 470-485.
  • Type: Conference Papers and Presentations Status: Published Year Published: 2018 Citation: Zivko Nikolov (keynote speaker), Production of Protein Hydrolysates and Bioactives from Microalgae. Food Tech Congress, Keynote lecture, Novi Sad, Serbia, October 2018
  • Type: Conference Papers and Presentations Status: Published Year Published: 2018 Citation: Laura Soto-Sierra, Sayali Kulkarni, Zivko Nikolov, Strategies for the Development of Microalgae-based Protein Products, Conference on Food Engineering, Minneapolis, MN, October 2018.
  • Type: Conference Papers and Presentations Status: Published Year Published: 2018 Citation: Zivko Nikolov, Laura Soto-Sierra, Sayali Kulkarni, , Production of protein concentrates and hydrolysates from the microalgae Chlorella vulgaris: A closer look at economics. 2018 Algal Biomass Summit, Houston, TX, October 2018.