Source: GROSS-WEN TECHNOLOGIES, LLC. submitted to
DERIVING A NEW BIOBASED PRODUCT FROM WASTEWATER: PRODUCTION OF A SLOW RELEASE ALGAL-BASED FERTILIZER
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
1013200
Grant No.
2017-33610-27018
Cumulative Award Amt.
$600,000.00
Proposal No.
2017-03464
Multistate No.
(N/A)
Project Start Date
Sep 1, 2017
Project End Date
Aug 31, 2020
Grant Year
2017
Program Code
[8.8]- Biofuels and Biobased Products
Recipient Organization
GROSS-WEN TECHNOLOGIES, LLC.
134 WATERFRONT DR
AMES,IA 50010
Performing Department
(N/A)
Non Technical Summary
The goal of this project is to continue the success of our Phase I proof-of-concept work by implementing a full-scale, algal-based treatment system to remove nutrients (such as nitrogen and phosphorus) from wastewater in small rural communities and to produce a pelletized, slow-release algal fertilizer as a value-added byproduct.Problem/Opportunity:Nutrient pollution in our nation's waterways is a major issue. These nutrients, which stem mainly from municipalities and agriculture, are causing environmental problems such as fish kills and toxic cyanobacteria blooms. To address this issue, state and federal agencies are enforcing stricter nutrient discharge limits for municipalities. These regulations result in a growing need for improved technologies such as our algal system (especially in rural communities). Furthermore, the current methods for generating fertilizer are not sustainable and are energy-intensive. New biobased fertilizer options are desired, and the algal-based fertilizer developed in this project addresses that need.Project Objectives:This Phase II SBIR is designed to produce and collect the remaining data needed to prove to our customers (rural communities) and their professional advisers that our process is reliable, cost-effective, and environmentally friendly. The major objectives of this project are to (1) build and evaluate a full-scale algal treatment system, (2) determine the best method to process algae into a saleable pelletized fertilizer, (3) evaluate the algae fertilizer in plant-growth studies, and (4) conduct an economic and life-cycle analysis of our proprietary algal treatment to fertilizer process. Following this Phase II project, our process will be ready for commercial deployment.
Animal Health Component
80%
Research Effort Categories
Basic
10%
Applied
80%
Developmental
10%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
1330210101060%
1020110101010%
4020210202030%
Goals / Objectives
Objective 1: Design, construct, and startup a full-scale RAB treatment system: We will design, install, start-up, and debug the RAB system at full-scale. We anticipate identifying unforeseen challenges related to building and operating a RAB system. Key information for designing, manufacturing, and installing the RAB system will be gained. This objective will be critical to identify accurate costs for manufacturing and installing the RAB system at full-scale, thereby providing us with the information needed to develop an accurate cost structure for selling the RAB system.Objective 2: Monitor the performance of a full-scale RAB system over a 12-month period: We will evaluate the efficiency and capacity of a full-scale RAB system. This system will be located at a municipal treatment lagoon in Dallas Center, IA. During this 12-month evaluation, important pollutant removal parameters will be determined. Removal performance will be evaluated throughout the year against changing environmental parameters due to seasonality. The impact of infiltration and inflow (I&I) on treatment capacity will also be determined. Biomass productivity will be evaluated during this year period. The major outcome of this objective will be full-year operational data that can be used to demonstrate the efficiency, capacity, costs, and reliability of the RAB system to regulatory agencies and our customers.Objective 3: Development of a saleable algal fertilizer product: We will convert the algae grown on wastewater into a storable, transportable, and easy to apply slow-release fertilizer pellet. Since the algae produced will be generated from raw municipal wastewater, it will be considered a biosolid that must be stabilized before being sold. We will evaluate approved biosolid stabilization methods to treat algal biomass and determine the most economical method. Different drying methods will be evaluated for moisture removal from the algal biomass to determine the most efficient method. Low-value, dry biochar will also be blended with algae to reduce or eliminate the need for drying prior to pelletization. The stabilized, dried, and pelletized material will be evaluated for desirable fertility parameters such as N, P, K content and undesirable parameters such as toxic metals and pathogens. The major outcome for this objective is to identify the most energy-efficient, cost-effective, and high-throughput method to process the wastewater-grown algae into a saleable fertilizer product.Objective 4: Perform a plant growth trial using pelletized algae fertilizer: The pelletized algal fertilizers generated in objective 3 will be tested in a plant growth trial. A pure algae pellet and an algae-biochar blend pellet will be evaluated. These fertilizers will be evaluated against COTS synthetic and organic fertilizers. Marigold, tomato, and turf grass will be used to test the fertilizers. These trials will take place at Iowa State University (ISU). The algal fertilizers will be considered successful if they attain equal/better plant growth results compared to the COTS fertilizers.Objective 5: Evaluate the economics and environmental impact of the RAB treatment process coupled with slow-release fertilizer production: The entire water treatment-to-algal fertilizer process will be evaluated. Throughout objectives 1-4, important parameters relating to treatment capacity, fertilizer efficiency, costs and environmental impact will be gathered. These values will be put into an economic model to determine the complete capital and operating costs for this process. Furthermore, the environmental impact parameters identified will be used to determine energy consumption, CO2 sequestration, and greenhouse gas emissions. The major outcome of this objective will be to provide our customers the treatment capacity, fertilizer efficiency, cost structure, and environmental impact required for a full-scale RAB-to-fertilizer process.
Project Methods
Objective 1: Design, construct and startup a full-scale RAB systemObjective 1, Task 1: Manufacture and Evaluate One RAB Module:The initial design work for the full-scale RAB system will be completed prior to this Phase II project commencement. Once this project starts, one RAB module (Figure 6A) will be built. This RAB module will be evaluated by GWT and Doerfer staff to determine if there are design improvements that must be made prior to manufacturing the remaining 21 modules. When evaluating the RAB unit, it will be stress tested to validate motor size, bearing durability, and structural integrity of the frame. During this test, we will run the system under full load for two weeks and then take it apart to identify faulty parts. The reactor will be reassembled and this process will be repeated until the reactor has no faulty parts and no more improvements are identified.Objective 1, Task 2: Install and Start Up the Full-scale RAB SystemDuring the installation and startup period, each aspect of the process will be carefully tested and evaluated. All parts will be evaluated for functional operation, durability, and ease of maintenance. The costs associated with all hardware and installation will be documented. The deliverables at the end of this objective will be: (1) determine accurate manufacturing and installation costs for a full-scale RAB system installation and (2) a functional full-scale RAB system that can be evaluated in objective 2 (12-month evaluation of RAB system performance).Objective 2: Monitor the performance of a full-scale RAB system over a 12-month periodWe will evaluate the efficiency and capacity of a full-scale RAB system. This system will be located at a municipal treatment lagoon in Dallas Center, IA. Important treatment pollutant removal parameters will be determined during this 12-month evaluation. These parameters include removal capacities and efficiencies for ammonia, nitrate, total N, total P, and COD. These will be evaluated throughout the year against the changing environmental parameters due to seasonality. The impact of I&I, which is caused by rainwater entering wastewater sewers, on treatment capacity will also be determined. The biomass productivity will be evaluated during this 12-month period.Objective 3: Development of a saleable algal fertilizer productWe will convert the algae grown on wastewater into a storable, transportable, and easy to apply slow-release fertilizer pellet. Since the algae produced will be generated from raw municipal wastewater, it will be considered a biosolid, and may contain pathogens, it must be stabilized before being sold. In this objective, we will evaluate the use of different approved biosolid stabilization methods to treat algal biomass and determine the most economical one. Different drying methods will also be evaluated to remove moisture from the algal biomass to determine the most efficient one. Low-value, dry biochar will be blended with the algae to decrease the need for drying. Following processing, the pellets will be evaluated for desirable fertility parameters such as N, P, and K content as well as undesirable parameters such as toxic metals and pathogens.Objective 4: Perform a plant growth trial using pelletized algae fertilizerThe pelletized algal fertilizer generated in objective 3 will be used in plant growth trials in this objective. The algae-based fertilizers to be evaluated are pure algae pellet and algae-biochar blend pellet. These fertilizers will be evaluated against COTS synthetic and organic fertilizers, and a control with no fertilizer addition. The plants that will be tested are marigold, tomato, and turf grass. These trials will take place at an ISU research plot.Objective 5: Evaluate the economics and environmental impact of the RAB treatment process coupled with slow-release fertilizer productionIn this objective, the entire water treatment-to-algal fertilizer process will be evaluated. During objectives 1-4 data about wastewater treatment capacity, pellet processing, costs, and environmental impact will be collected. These values will be put into an economic model to determine the capital and operating costs associated with this process. Also, the environmental impact parameters that are identified will be used to determine energy consumption, CO2 sequestration, and greenhouse gas (GHG) emissions.

Progress 09/01/17 to 08/31/20

Outputs
Target Audience:The target audience for this proposal are any entity that is interested in new wastewater treatment technologies. This includes municipalities or industries that are currently treating wastewater. This also includes engineering firms that design water treatment plants. Additionally the target audience are groups interested in alternative biomass materials/ fertilizer. Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided?Training activities: multiple internship positions of research associates were provided to engineering student/graduates. Professional development: reports on Algal biomass summit, Water environment federation How have the results been disseminated to communities of interest?Pilot-, Demo-, and Commercial-scale RAB installation and testing in multiple publicly owned treatment works; Communication and collaboration with first-in-class researchers across USA Collaborations with algal material manufacturing companies as an algae farmer What do you plan to do during the next reporting period to accomplish the goals? Nothing Reported

Impacts
What was accomplished under these goals? Objective 1: Over the past three years, an 8-belt commercial-scale algal biofilm system has been fabricated, constructed, installed, and tested in the City of Slater, IA. This system has successfully past the initial 2-month preliminary test. A model was made to estimate the winterization cost as ~$5k/module/year. Objective 2: Now the reactorhas been formally running for one and half year in municipal wastewater treatment. The primary effluent from Slater was pumped to the full-scale RAB reactor at a flow rate ranging from 0.08 to 0.23 million gallon per day (MGD) for nutrients removal. The Ammonia (NH3), total nitrogen (TN), total phosphorus (TP) and chemical oxygen demand (COD) in the influent and effluent have been closely monitored throughout the configurations test, mixing systems comparison, and the flow rates test. NH3 concentration in influent ranged from 5.96 mg/L to 54.5 mg/L. TN concentration in influent ranged from 16.2 mg/L to 62.14 mg/L. TP concentration in influent ranged from 1.29 mg/L to 7.24 mg/L. COD concentration in influent ranged from 56.2 mg/L to 681 mg/L. It was found that the RAB system can achieve a nutrient removal efficiency of 2~75% (NH3), 8~29%(TN), 8~28%(TP), and 31~67% (COD); and a belt surface area (m2) daily removal rate of, 6.53 g/m2/day (NH3), 3.23 g/m2/day (TN), 0.58 g/m2/day of TP and 73.18 g/m2/day (COD). Objective 3: The biomass harvested from this commercial-scale algal biofilm system was dried, pelletized, and stored to make a slow-release fertilizer product. The protocols for dring, pelletizing and storage were optimized. This wastewater-derived fertilizer is identified as Class A biosolids after the evaluation of pathogen, inorganic pollutants, as well as vector attraction reduction. GWT has registered this fertilizer product (NO. PD 17580) at Department of Agriculture & Land Stewardship, IA. Objective 4: In addition, this slow-release fertilizer product has been applied in a turf-grass culture study to evaluate the performance of the wastewater grown algae compared to off-the-shelf chemical fertilizer options. The GWT Blended Pellets performed better than the other fertilizers in categories of total root length, root surface area and root volume. The blended pellets offered the most holistic improvements to overall turf health. This demonstrates how algae-based fertilizers are an excellent method to improve turfgrass health. Objective 5: The LCA/TEA work has been done as well. The case study included in this LCA/TEA analysis showed that for a wastewater treatment plant with 0.5 MGD of flow rate, 3 10-belt RAB module could facilitate the WWTP to achieve over 90% of pollutants removal, at an averaged cost of $3.85 per pound of nutrient removed. Each year a commercial RAB system will use 48,783 kWh of electricity, sequester 19.5 tons of CO2, and produce approximately 23 metric tons of algae-based fertilizer ready for sale.

Publications


    Progress 09/01/18 to 08/31/19

    Outputs
    Target Audience:The target audience for this proposal are any entity that is interested in new wastewater treatment technologies. This includes municipalities or industries that are currently treating wastewater. This also includes engineering firms that design water treatment plants. Additionally the target audience are groups interested in alternative biomass materials that can be made into new products. Additionally groups interested in alternative fertilizers. Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided? Nothing Reported How have the results been disseminated to communities of interest? Nothing Reported What do you plan to do during the next reporting period to accomplish the goals?Objective 1: done Objective 2:The RAB system will be changed to series configuration and continue to run for another 7 months for primary treatment. Objective 3: Done Objective 4: Complete the turfgrass field trial test to evaluate the wastewater-derived fertilizer performance in plant culture. Objective 5: The TEA/LCA will be done when the 12-month operating of full-scale RAB system in treating municipal wastewater. LCA: GWT plans to continue the literature review of related LCA's to gain a better understanding of what is typical for LCA's in related fields. The next step will be to define the scope for this process to limit the amount of considerations needed to complete the assessment. TEA: GWT will continue to reach out to vendors to get quotes for equipment needed in the pelleting process. Additionally, a model will be developed to demonstrate the cost to produce one ton of saleable algae fertilizer. This model will allow for adjustments in the flow of raw feedstock, cost of energy, and value of the fertilizer. One of the main goals of this model will be to determine the minimum selling price of the fertilizer to make a profit.

    Impacts
    What was accomplished under these goals? Over the past year, an 8-belt commercial-scale algal biofilm system has been established and tested in the City of Slater, IA. This system has successfully past the initial 2-month preliminary test. Now it has been formally running for half year in municipal wastewater treatment. The primary effluent from Slater was pumped to the full-scale RAB reactor at a flow rate of 0.231 mega gallon per day (MGD) for nutrients removal. The Ammonia (MH3), total nitrogen (TN), total phosphorus (TP) and chemical oxygen demand (COD) in the influent and effluent are closed monitored. The full-scale RAB system with a parallel configuration can achieve removal efficiency of, 29% (NH3), 14% (TN), 20% (TP), and 40% (COD), respectively. Furthermore, it was found that the RAB system can achieve a belt surface area (m2) daily removal rate of, 6.5 g/m2/day (NH3), 3.3 g/m2/day (TN), 1.8 g/m2/day of TP and 73.2 g/m2/day (COD). The biomass harvested from this commercial-scale algal biofilm system was dried, pelletized, and stored to make an off-the-shelf slow-release fertilizer product. This wastewater-derived fertilizer is identified as Class A biosolids. GWT has registered this fertilizer product (NO. PD 17580) at Department of Agriculture & Land Stewardship, IA, after a comprehensive evaluation of the biomass. In addition, this slow-release fertilizer product has been applied in a turf-grass culture study to evaluate the performance of the wastewater grown algae compared to off-the-shelf chemical fertilizer options. The LCA/TEA work is initialized and will be done when the 12-month running of the full-scale RAB system is done.

    Publications


      Progress 09/01/17 to 08/31/18

      Outputs
      Target Audience:The target audience for this proposal are any entity that is interested in new wastewater treatment technologies. This includes municipalities or industries that are currently treating wastewater. This also includes engineering firms that design water treatment plants. Additionally the target audience are groups interested in alternative biomass materials that can be made into new products. Additionally groups interested in alternative fertilizers. Changes/Problems:We intended to install the RAB system in Dallas Center, IA for our commercial scale system. However they had to move forward with another technology and were not able to install our system. We instead will install the commcercial scale system at another similar location. The manufacturing of the RAB has taken longer than expected and several bugs are being worked out before deployment. Both of these issues will not influence the major outcome of this work which is validation at commercial scale at a small community in IA. What opportunities for training and professional development has the project provided? Nothing Reported How have the results been disseminated to communities of interest? Nothing Reported What do you plan to do during the next reporting period to accomplish the goals?Objective 1: Design, construct, and startup a full-scale RAB treatment system: Next Steps: Upon finishing of the 8-belt module it will be stress tested in house at Doerfer Industries and then shipped out for installation at a wastewater treatment plant. Once installed we will test and identify different methods to transport the algae out of the greenhouse. Objective 2: Monitor the performance of a full-scale RAB system over a 12-month period: We intend to deploy this in a location near Ames. This will occur in the second half of the project. Objective 3: Development of a saleable algal fertilizer product: Next Steps: Next steps will be to test for volatile solids and perform above studies to the algal biomass at a different location in Iowa. Objective 4: Perform a plant growth trial using pelletized algae fertilizer: Perform field study and turf study during second half of project. Objective 5: Evaluate the economics and environmental impact of the RAB treatment process coupled with slow-release fertilizer production Data is still being collected for Objective 5. Executing this portion of the project cannot occur until all data points have been collected.

      Impacts
      What was accomplished under these goals? In this USDA SBIR Phase II project, research has been conducted to evaluate methods for drying and pathogen reduction of the algae biomass. In addition, a greenhouse plant growth study was performed to evaluate the performance of the treated wastewater grown algae compared to off the shelf fertilizer options. Doerfer Industries is in the final stages of manufacturing the full-scale Revolving Algal Biofilm (RAB) system module. Upon completion of assembly this will be tested in house for 1-2 months and then deployed to a wastewater treatment facility for analysis. We have evaluated the processes to further reduce pathogens (PFRP) outlined in EPA 503 biosolids including: pasteurization treatment, heat treatment, composting treatment, and lime treatment. We have identified that all methods can be used to reduce pathogen levels to below the 1000 most probable number (MPN) threshold. This threshold is one of the criteria to achieve a Class A Biosolid algae. In addition we conducted ICP analysis to find the concentration of heavy metals in the biosolids. These were all found, except in rare cases, to also meet the Class A Biosolids. The only further analysis that will be required is vector attraction reduction which will be carried out in the second half of the project. We also intend to validate these results at another plant in Iowa. After performing the PFRP the algae was used as a slow release fertilizer in a greenhouse study comparing it to off-the-shelf options. The results are clear that algae performs just as well if not better then all of the other fertilizers evaluated. The next step in evaluating the fertilizer will be a field study and this will be performed in spring of 2019. We attempted to perform it in spring of 2018 but due to abnormally high amounts of rain the test plot we had identified was underwater. Doerfer Industries, the manufacture of the RAB system, has already identified and corrected several issues with the full-scale RAB system. One of the most notable improvement is the addition of speed sensors. These sensors are located on all four corners of the RAB system and indicate the speed of each shaft. This is crucial because if any shaft is rotating faster or slower than the others it means a catastrophic failure may occur. It instantly shuts down the RAB system before any damage can be done. In short, the project has been a great success thus far. The next year of the project will reveal important information for moving forward with commercializing the RAB system and handling and processing the algae coming off the belts.

      Publications