Progress 11/06/14 to 09/30/18
Outputs
Target Audience: Livestock and poultry industry. Local, state, federal, and international regulatory agencies. Farmers. Students. Scientists. Engineers. Changes/Problems:
Nothing Reported
What opportunities for training and professional development has the project provided? International collaboration. Engaging stakeholders in industry, livestock farming. S-1032 meeting and networking opportunities. Further networking: INFEWS project (co-PI: Koziel) "INFEWS/T4: The INFEWS-ER: a Virtual Resource Center Enabling Graduate Innovations at the Nexus of Food, Energy, and Water Systems" (Jan 2017 - Dec 2020). How have the results been disseminated to communities of interest? over 50 peer-reviewed journal articles published over 60 invited (keynote and workshop) presentations related to air quality and livestock operations were made in Canada, Poland, and Republic of Korea. What do you plan to do during the next reporting period to accomplish the goals?
Nothing Reported
Impacts
What was accomplished under these goals?
IMPACT: Our project addressed several problems related to livestock agriculture and diversification of agriculture. These include (1) solving the livestock odor problem and improving air quality, (2) improving practical field-based environmental assessment, (3) pioneering research in finding biomarkers bovine diseases that are most impactful economically to US beef cattle industry, and (4) pioneering farming for flavor for cold-hardy grapes grown in U.S. Midwest. Through our research, knowledge was increased in all these areas. Objective (1) Engage collaborators from the needed broad range of disciplines, institutions, and stakeholder groups to catalyze conceptual and quantitative synthesis, collaboration, and data sharing. Collaborators from a broad range of disciplines, institutions, and stakeholder groups were engaged and catalyzed conceptual and quantitative synthesis, collaboration and data sharing. Specifally, agricultural engineers, animal scientists, chemists, agronomists, toxicologists, veterinarians were collaborating. Over 10 international scientists from Kazakhstan, Poland, Republic of Korea, were engaged. Stakeholders from other universities, industry, national laboratories were engaged. Over 50 peer-reviewed publications in highly impactful journals were published. Major progress was made to address several problems related to livestock agriculture and diversification of agriculture. These include (1) solving the livestock odor problem and improving air quality, (2) improving practical field-based environmental assessment, (3) pioneering research in finding biomarkers bovine diseases that are most impactful economically to US beef cattle industry, and (4) pioneering farming for flavor for cold-hardy grapes grown in U.S. Midwest. Objective (2) Discover (or reveal), substantiate, and interpret the broader impacts of component-level modifications to animal-production systems. Farm-proven treatment for mitigation of gaseous emissions from deep pit swine manure storage was developed. The treatment uses readily available soybean hulls that are applied to the manure surface. Significant reduction in emissions of ammonia, hydrogen sulfide and major odorous volatiles were observed in farm-scale trials. The cost of treatment is below median for comparable mitigation technologies. Pioneering research to adapt advanced oxidation technologies (i.e., UV light) to mitigate odor, volatile organic compounds, ammonia, and hydrogen sulfide emissions from livestock operations was initiated and lab and pilot-scales. Fast disposal of animal mortalities in the event of pandemic outbreak of infectious diseases and the need to rapidly dispose massive amounts of mortalities was developed in lab-scale. Effective disposal of swine carcasses was developed using on-farm composting with readily available biomass. Cold-hardy grapes can be farmed for flavor. This means that certain desirable aromas in wines produced from these Midwest cultivars can be exploited using various viticultural approaches as well as wine-making practices. Pioneering work on cold-hardy grapes and associated wines was completed. More research is still needed to bring these local grapes and wines to the recognition they deserve. Multiple media reports in global media outlets, local press, industry bulletins and global newspapers were published about research with UV light to solve the livestock odor problem and about developed concept of improved in-trench burial for animal mortalities.
Publications
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Maurer, D.L, A. Bragdon, B. Short, H.K. Ahn, J.A. Koziel. 2018. Improving environmental odor measurements: comparison of lab-based standard method and portable odour measurement technology. Archives of Environmental Protection, 44(2), 100-107. doi: 10.24425/119699.
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Maurer, D., J.A. Koziel, T.J. Engelken, V.L. Cooper, J.L. Funk. 2018. Detection of volatile compounds emitted from nasal secretions and serum: Towards non-invasive identification of diseased cattle biomarkers. Separations, 5(1), 18. doi: 10.3390/separations5010018.
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Rice, S., N. Lutt, J.A. Koziel, M. Dharmadhikari, A. Fennell. 2018. Determination of selected aromas in Marquette and Frontenac wine using headspace-SPME coupled with GC - MS and simultaneous olfactometry. Separations, 5(1), 20. doi: 10.3390/separations5010020
- Type:
Book Chapters
Status:
Published
Year Published:
2018
Citation:
Criddle, W.J., Koziel, J.A., van Leeuwen, J.H., Jenks, W.S. Ethanol. Encyclopedia of Analytical Science, Reference Module in Chemistry, Molecular Sciences and Chemical Engineering, Elsevier, Third edition, 2018. Doi: 10.1016/B978-0-12-409547-2.14560-3.
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Koziel, J.A., H.K. Ahn, T.D. Glanville, T.S. Frana, H. van Leeuwen, L.T. Nguyen. 2018. Lab-scale evaluation of aerated burial concept for treatment and emergency disposal of infectious animal carcasses. Waste Management,76, 715-726. doi: 10.1016/j.wasman.2018.03.009.
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Arena, U., M. Barlaz, P. He, I.I. D'Adamo, S. Astals, J.E. Bogner, S.C. Bolyard, J.M.C. L. de Brito, P.S. Calabr�, P. Canu, C. Chroni, B. Clarke, H. Corvellec, G. Costa, M.R Gent, A.G. Izquierdo, J.A. Koziel, N. Lapa, B. Leckner, L. Lombardi, M. Materazzi, H. Oonk, K. Pivnenko, K.R. Reddy, H. van der Sloot, J.O. Sundqvist, F. Tat�no, T. Townsend, D. Turner, J. Vehlow, T. Wang, Y. Wang, J. White, Y. Zeng, C. Zurbr�gg. 2018. Thank you: A journal is as good as its reviewers. Waste Management, 77(7): iii-vi. doi: 10.1016/j.wasman.2018.06.050
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Bialowiec, A., M. Micuda, A. Szumny, J. ?yczko, J.A. Koziel. 2018. Quantification of VOCs emissions from carbonized refuse-derived fuel using solid-phase microextraction and gas chromatography mass spectrometry. Molecules, 23(12), 3208; doi: 10.3390/molecules23123208
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Koziel, J.A., H.K. Ahn, T.D. Glanville, T.S. Frana, H. van Leeuwen, L.T. Nguyen. 2018. Data evidencing slow anaerobic digestion in emergency treatment and disposal of infectious animal carcasses. Data in Brief, doi: 10.1016/j.dib.2018.12.001.
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Bialowiec, A., M. Micuda, J.A. Koziel. 2018. Waste to carbon: densification of torrefied refuse-derived fuel. Energies, (11)11, 3233; doi: 10.3390/en11113233.
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Kenessov, B., J.A. Koziel, N. Baimatova, O.P. Demyanenko, M. Derbissalin. 2018. Optimization of time-weighted average air sampling by solid-phase microextraction fibers using finite element analysis software. Molecules, 23(11), 2736; doi:10.3390/molecules23112736
- Type:
Journal Articles
Status:
Published
Year Published:
2018
Citation:
Orazbayeva, D., B. Kenessov, J.A. Koziel. 2018. Quantification of naphthalene in soil using solid-phase microextraction, gas-chromatography with mass-spectrometric detection and standard addition method. International Journal of Biology and Chemistry, 11(1), 4-11. doi: 10.26577/ijbch-2018-1-295 http://ijbch.kaznu.kz/index.php/kaznu/article/view/295
|
Progress 10/01/16 to 09/30/17
Outputs
Target Audience: Livestock and poultry industry. Local, state, federal, and international regulatory agencies. Farmers. Students. Scientists. Engineers. Changes/Problems:Dr. Daniel Andersen has been added as a co-PIto the project. What opportunities for training and professional development has the project provided?S-1032 meeting and networking opportunities in summer of 2017. Further networking related to NSF-funded INFEWS project (co-PI: Koziel) "INFEWS/T4: The INFEWS-ER: a Virtual Resource Center Enabling Graduate Innovations at the Nexus of Food, Energy, and Water Systems" (Jan 2017 - Dec 2020). How have the results been disseminated to communities of interest? 20 peer-reviewed journal articles published (1 awaiting publication and 1 submitted). 1 disclosure of invenstion. 11 conference presentations made. 2 invited (keynote or opening plenary) presentations abroad made (Poland, Spain). 1 distinguished lecture at the Annual International Meeting of the ASABE, Spokane, WA, 2017. What do you plan to do during the next reporting period to accomplish the goals? Publish 15 peer-reviewed papers. Disseminate results from previous and on-going projects. Leverage publications to solicit research funding. Complete deliverables for the NSF-funded INFEWS project "
Impacts
What was accomplished under these goals?
Overall Impact Statement: Major progress was made to solve the livestock odor problem.Odor mitigation technologies were tested in lab-scale, pilot-scale, and farm-scale.Results were published in peer-reviewed publications of which many are in open-access format. Maurer et al (2017) showed that soybean peroxidase (SBP), a bio-based, soybean-derived pit manure additive worked in farm-scale and mitigated ammonia, hydrogen sulfide, volatile organic compound emissions without significant increase in nitrous oxide emissions. All this was accomplished for below the average cost of comparable, claimed products. Maurer et al (2017) showed thatbiochar can be effectively used as a pit swine manure additive to mitigate ammonia emissions from swine manure in pilot-scale study. Zhu et al (2017) showed that black light can effectively reduce livestock odor in lab-scale study. NSF INFEWS project (co-PI: Koziel) "INFEWS/T4: The INFEWS-ER: a Virtual Resource Center Enabling Graduate Innovations at the Nexus of Food, Energy, and Water Systems" (Jan 2017 - Dec 2020) was initiated.Kick-off meeting was completed in April 2017.The preparations for the 1st year Symposium (March 2018) are on-going. Speficically for Objective 1:Engage collaborators from the needed broad range of disciplines, institutions, and stakeholder groups to catalyze conceptual and quantitative synthesis, collaboration, and data sharing. Dr. Heekwon Ahn, Professor at Chungnam National University in South Korea, completed sabbatical project "Research in measurement and control of livestock odor' (Aug, 2016 - August 2017). This collaboration resulted in three peer-reviewed publications in highly impactful journals (published or accepted) and one in preparation. Major progress was made on early detection of bovine infectious diseases in collaboration with scientists from the National Animal Disease Center in Ames, IA and USDA- APHIS-WS-National Wildlife Research Center in Fort Collins, CO. Microbial cultures, feces, and breath biomarkers were identified warranting further development of approaches for non-invasive, fast detection of animal diseases. One journal publications was published and one is in review. Specifically for Objective 2: Discover (or reveal), substantiate, and interpret the broader impacts of component-level modifications to animal-production systems. The research project focused on wet scrubber and advance oxidation technologies to mitigate particulate matter, odor, volatile organic compounds, ammonia, and hydrogen sulfide emissions from livestock operations is completed.One peer-reviewed paper was published in open-access format following the lab-scale studies. Lab-scale studies focused on advances oxidation and comparisons of two photoactive special coatings for interior barn surfaces. Completed experiments revealed that the reduction of major odorants, i.e., butyric acid and p-cresol were 82.8±16.2% and 93.9±2.1% respectively with novel PureTi coat that is nearly as effective as 25x thicker conventional titanium coating.The novel PureTi coat is a more efficient option for black light photocatalysis, and can yield high reduction rates of odorant VOCs (especially p-cresol).Multiple media reports in local press, industry bulletins and global newspapers were published about this work. Manuscript from the pilot-scale work is in preparation.Non-functionalized biochar was also pioneered as a pit swine manure additive in pilot-scale and showed to be effective in mitigating ammonia emissions.A soybean based product was also farm-tested as a pit swine manure additive and showed to be effective in mitigating ammonia, hydrogen sulfide, and odorous gas emissions for approximate $1.45/finisher pig.
Publications
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Surface application of soybean peroxidase and calcium peroxide for reducing odorous VOC emissions from swine manure slurry. Applied Engineering in Agriculture, 32(4), 389-398. DOI: 10.13031/aea.32.11672.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Kenessov, B., J.A. Koziel, N. Baikakina, D. Orazbayeva. 2016. Perspectives and challenges of on-site quantification of organic pollutants in soils using solid-phase microextraction. Trends in Analytical Chemistry, 85, 111-122.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Onuki, S., J.A. Koziel, W.S. Jenks, L. Cai, D. Grewell, J.H. van Leeuwen. 2016. Taking ethanol quality beyond fuel grade: a review. Journal of the Institute of Brewing, 122(4), 588-598. DOI: 10.1002/jib.364.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Parker, D.B., M.B. Rhoades, B.H. Baek, J.A. Koziel, H.M. Waldrip, R.W. Todd. 2016. Urease inhibitor for reducing ammonia emissions from an open-lot beef cattle feedyard in the Texas High Plains. Applied Engineering in Agriculture, 32(6), 823-832. DOI: 10.13031/aea.32.11897.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Koziel J.A., T.S. Frana, H.K. Ahn, T.D. Glanville, L.T. Nguyen, H. van Leeuwen. 2017. Efficacy of NH3 as a secondary barrier treatment for inactivation of Salmonella Typhimurium and methicillin-resistant Staphylococcus aureus in digestate of animal carcasses: Proof-of-concept. PLoS ONE, 2017, 12(5): e0176825. doi: 10.1371/journal.pone.0176825.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Maurer, D., J.A. Koziel, K. Kalus, D. Andersen, S. Opalinski. 2017. Pilot-scale testing of non-activated biochar for swine manure treatment and mitigation of ammonia, hydrogen sulphide, odorous VOCs, and greenhouse gas emissions. Sustainability, 9(6), 929, doi: 10.3390/su9060929.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Zhu, W., J.A. Koziel, D.L. Maurer. 2017. Mitigation of livestock odors using a black light and a new titanium dioxide-based catalyst: proof-of-concept. Atmosphere, 8(6), 103. doi: 10.3390/atmos8060103.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Cai, L., S. Rice, J.A. Koziel, M. Dharmadhikari. 2017. Development of an automated method for selected aromas of red wines from cold-hardy grapes using solid-phase microextraction and gas chromatography - mass spectrometry olfactometry. Separations, 2017, 4(3), 24. doi: 10.3390/separations4030024.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Ellis, C., S. Rice, D. Maurer, R. Stahl, R. Waters, M. Palmer, P. Nol, J. Rhyan, K. VerCauteren, J.A. Koziel. 2017. Use of fecal volatile organic compound analysis to discriminate between non-vaccinated and BCG-vaccinated cattle prior to and after Mycobacterium bovis challenge. PLoS ONE, 2017, 12(7): e0179914. doi: 10.1371/journal.pone.0179914.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Baimatova, N, J.A. Koziel, B. Kenessov. 2017. Passive sampling and analysis of naphthalene in internal combustion engine exhaust with retracted solid phase microextraction device and GC-MS. Atmosphere, 8(7), 130. doi. 10.3390/atmos8070130.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Soso, S.B., J.A. Koziel. 2017. Characterizing the odor and chemical composition of scent-markings of Panthera leo and its link to behavior using solid-phase microextraction and multidimensional gas chromatography-mass spectrometry-olfactometry. Scientific Reports. 7(1):5137. doi: 10.1038/s41598-017-04973-2.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Koziel, J.A. Successful grant-writing strategies for junior scientists: An American public university perspective. Higher School's Pulse, 2016, 10(4), 21-25. doi: 10.5604/20812021.1225356.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Maurer, D., J.A. Koziel, K. Bruning, D.B. Parker. 2017. Pilot-scale testing of renewable biocatalyst for swine manure treatment and mitigation of odorous VOCs, ammonia, and hydrogen sulfide gas emissions. Atmospheric Environment, 150, 313-321. DOI: 10.1016/j.atmosenv.2016.11.021.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Dobrzanski, Z., B. Buszewski, S. Opalinski, R. Kolacz, J.A. Koziel. 2017. Xenobiotics, toxic compounds, mutagens and carcinogens substances classification and regulatory challenges. Przemysl Chemiczny. 96(1), 76-84. doi:10.15199/62.2017.1.5.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Maurer, D., J.A. Koziel, K. Bruning. 2017. Field scale measurement of greenhouse gas emissions from land applied swine manure. Frontiers of Environmental Science & Engineering, 2017, 11(3), 1, doi: 10.1007/s11783-017-0915-9.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Koziel, J.A., Nguyen, L.T., T.D. Glanville, H.K. Ahn, T.S. Frana, J.H. van Leeuwen. 2017. Method for sampling and analysis of volatile biomarkers in process gas from aerobic digestion of poultry carcass using time-weighted average SPME and GC-MS. Food Chemistry, 232, 799-807. doi: 10.1016/j.foodchem.2017.04.062.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Kalus, K., S. Opalinski, D. Maurer, S. Rice, J.A. Koziel, M. Korczynski, Z. Dobrzanski, R. Kolacz, B. Gutarowska. Odour reducing microbial-mineral additive for poultry manure treatment. Frontiers of Environmental Science & Engineering, 2017, 11(3), 7. doi: 10.1007/s11783-017-0928-4.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Orazbayeva, D., B. Kenessov, J.A. Koziel, D. Nassyrova, N.V. Lyabukhova. 2017. Quantification of BTEX in soil by headspace SPME-GC-MS using combined standard addition and internal standard calibration. Chromatographia, 80(8), 1249-1256. doi: 10.1007/s10337-017-3340-0.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Rice, S., J.A. Koziel, M. Dharmadhikari, A. Fennell. 2017. Evaluation of tannins and anthocyanins in Marquette, Frontenac, and St. Croix cold-hardy grape cultivars. Fermentation, 3(3), 47. doi: 10.3390/fermentation3030047.
- Type:
Journal Articles
Status:
Published
Year Published:
2017
Citation:
Maurer, D., J.A. Koziel, K. Bruning, D.B. Parker. 2017. Farm-scale testing of soybean peroxidase and calcium peroxide for surficial swine manure treatment and mitigation of odorous VOCs, ammonia, hydrogen sulfide emissions. Atmospheric Environment, 166, 467-478. doi: 10.1016/j.atmosenv.2017.07.048.
- Type:
Journal Articles
Status:
Awaiting Publication
Year Published:
2018
Citation:
Maurer, D.L, A. Bragdon, B. Short, H.K. Ahn, J.A. Koziel. 2017. Improving environmental odour measurements: comparison of lab-based standard method and portable odour measurement technology. Archives of Environmental Protection, accepted, in press for early 2018 issue.
- Type:
Journal Articles
Status:
Submitted
Year Published:
2018
Citation:
Maurer, D., C. Ellis, T. Thacker, S. Rice, J.A. Koziel, K.C. VerCauteren, P. Nol. Screening of microbial volatile organic compounds for detection of disease in cattle: development of lab-scale method. Scientific Reports, submitted.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
1. Maurer, D.L, A. Bragdon, B. Short, H.K. Ahn, J.A. Koziel. 2017. Improving environmental odour measurements: comparison of lab-based standard method and portable odour measurement technology. In the proceedings of the 7th International Water Association Conference on Odours and Air Emissions, Warsaw, Poland, September, 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Zhu, W., J.A. Koziel, D.L. Maurer. 2017. Mitigation of livestock odours using a black light and a new titanium dioxide-based catalyst: proof-of-concept. In the proceedings of the 7th International Water Association Conference on Odours and Air Emissions, Warsaw, Poland, September, 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Maurer, D.L., J.A. Koziel, K. Bruning, D.B. Parker. 2017. Pilot-scale concept of real-time wind speed-matching wind tunnel for measurements of gaseous emissions. ASABE Paper #1701656. 2017 ASABE Annual International Meeting, Spokane, Washington, July, 2017. doi: 10.13031/aim.201701656.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Maurer, D.L., J.A. Koziel, K. Bruning, D.B. Parker. 2017. Renewable biocatalyst for swine manure treatment and mitigation of odorous VOCs, ammonia and hydrogen sulfide emissions: Review. ASABE Paper #1701655. 2017 ASABE Annual International Meeting, Spokane, Washington, July, 2017. doi: 10.13031/aim.201701655.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Lessons learned from solving livestock odor problem: an American perspective. Plenary opening lecture. The 7th IWA Odour and Air Emissions Conference, Warsaw, Poland, September 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Odor and Odorous Chemical Emissions from Animal Buildings: Part 3- Chemical Emissions. Distinguished Lecture, ASABE Annual International Meeting, Spokane, WA, July 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Recent Developments in Time-weighted Average sampling of gases with retracted solid-phase microextraction. Keynote speaker. 19th International Symposium on Advances in Extraction Technologies, ExTech 2017, Santiago de Compostela, Spain, June 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Rice, S., Tursumbayeva, M., Dharmadhikari, M., Fennel, A., Koziel, J.A. 2017. Effects of harvest time on aroma of wines made from Brianna and Frontenac Gris grapes using gas-chromatography-mass-spectrometry and olfactometry. Presentation at the 42nd Annual Conference and Symposium of the American Society for Enology and Viticulture - Eastern Section; Charlottesville, VA, July, 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Kenessov, B., J.A. Koziel. 2017. Modelling of time-weighted average air sampling by retracted SPME fibers using COMSOL Multiphysics software. In the proceedings of the ExTech 2017 19th International Symposium of Advances in Extraction Technologies, Santiago de Compostela, June 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2017
Citation:
Tursumbayeva, M., J.A. Koziel, D.L. Maurer. 2017. Novel method for quantification of odorous volatiles in the air with solid-phase microextraction and gas chromatography mass spectrometry. Presentation at the 129th Annual Meeting of the Iowa Academy of Science & 84th Iowa Junior Academy of Science Symposium, Cedar Falls, IA, April 2017.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2016
Citation:
Swaminathan, P., A. Fennell, K. Besler, Y. Yao, S. Rice, J. Koziel, M. Dharmadhikari, D. Maurer, E. Del Bel, Z. Vickers, K. Cook, A. Hegeman, J. Luby. Characterization of grape berry ripening - genomics to sensory. Ninth RECOMB/ISCB Conference on Regulatory & Systems Genomics, with DREAM Challenges & Cytoscape Workshop, Phoenix, AZ, November 2016.
|
Progress 10/01/15 to 09/30/16
Outputs
Target Audience: Livestock and poultry industry Local, state, federal, and international regulatory agencies Farmers Students Scientists Engineers Changes/Problems:
Nothing Reported
What opportunities for training and professional development has the project provided?U.S. Fulbright Scholar (PI: Koziel) in Poland (ended in June 2016). Project: Enhancing STEM Collaborations with Wroclaw University of Environmental and Life Sciences'. How have the results been disseminated to communities of interest? 15 peer-reviewed journal articles published (7 awaiting publication and 3 submitted). 12 international conference presentations made. 21 invited presentations abroad made (Poland, Ukraine). Air Management Practices Assessment Tool (AMPAT) website (ISU Extension and Outreach) was updated with published journal article on the summarizing performance data for technologies to control gaseous, odor, and particulate emissions from livestock operations (Maurer et al, Data in Brief, 7, 1413-1429. doi: 10.1016/j.dib.2016.03.070.) What do you plan to do during the next reporting period to accomplish the goals?Publish approximately 25 peer-reviewed journal articles in highly ranked journals to: Disseminate results from previous and on-going projects. Leverage publications to solicit research funding. Complete deliverables for the NSF-funded INFEWS project.
Impacts
What was accomplished under these goals?
IMPACT: The livestock industry needs a suite of robust technologies to address gaseous emissions -- technologies to minimize the carbon/nitrogen footprint, address climate change and adaptation to climate change, and improve the sustainability and global competitiveness of the US livestock industry as a steward of resources. This project period major progress was made to solve the livestock odor problem. The first resulting peer-review publication reporting on in is awaiting publication in 2017. Maurer et al showed that soybean peroxidase (SBP), a bio-based, soybean-derived, mitigates ammonia emissions up to 68%, major odorous volatiles up to 90%, without significant increase in nitrous oxide emissions. All this for below the average cost of comparable, claimed products. Field studies at a swine farm were consistent with pilot-scale results. Also, networking with the S-1032 committee enabled proposal completion and successful funding of the NSF INFEWS project (co-PI: Koziel) "INFEWS/T4: The INFEWS-ER: a Virtual Resource Center Enabling Graduate Innovations at the Nexus of Food, Energy, and Water Systems" (Jan 2017 - Dec 2020). Objective 1... Engage collaborators from the needed broad range of disciplines, institutions, and stakeholder groups to catalyze conceptual and quantitative synthesis, collaboration, and data sharing Fulbright Scholarship project "Enhancing STEM Collaborations with Wroclaw University of Environmental and Life Sciences" enabled engaging collaborators, junior scientists and doctoral students from several major agriculture-focused universities in Poland. One Ph.D. student from Poland completed Kosciuszko Foundation-funded project "Research in mitigation of livestock odor' at Iowa State University. Dr. Heekwon Ahn, Associate Professor at Chungnam National University in South Korea, started sabbatical project "Research in measurement and control of livestock odor' (Aug, 2016 - January 2017). Major progress was made on early detection of bovine infectious diseases in collaboration with scientists from the National Animal Disease Center in Ames, IA and USDA- APHIS-WS-National Wildlife Research Center in Fort Collins, CO. Microbial cultures, feces, and breath biomarkers were identified warranting further development of approaches for non-invasive, fast detection of animal diseases. Two journal publications are in review. Objective 2... Discover (or reveal), substantiate, and interpret the broader impacts of component-level modifications to animal-production systems. Major scientific research involving review of 250+ journal papers focused on mitigation technologies for odor, gas and particulate matter emissions from livestock production was completed. Results were published in an Open Access (Maurer et al, Data in Brief, 2016). The study showed that only approximately only ~25% of research on mitigation technologies for odor, gases and particulate emissions from livestock farming was tested in field/farm conditions. The majority of research was completed for swine. More research is needed to move promising technologies from lab/pilot-scale to farm/field scales. The published study and associated data base (in form of spreadsheets) is an integral part of Extension website "Air Management Practices Assessment Tool (AMPAT) at Iowa State University serving public, farmers, livestock industry, regulatory agencies and other stakeholders. In addition, a conference paper summarizing odor control legislation in the world was completed and presented at an international odor conference in Poland (Bokova et al., 2016). The research project focused on wet scrubber and advance oxidation technologies to mitigate particulate matter, odor, volatile organic compounds, ammonia, and hydrogen sulfide emissions from livestock operations is mid through completion. Lab-scale studies focused on advances oxidation and comparisons of two photoactive special coatings for interior barn surfaces. Completed experiments revealed that the reduction of major odorants, i.e., butyric acid and p-cresol were 82.8±16.2% and 93.9±2.1% respectively with novel PureTi coat that is nearly as effective as 25x thicker conventional titanium coating. The novel PureTi coat is a more efficient option for black light photocatalysis, and can yield high reduction rates of odorant VOCs (especially p-cresol). Farm-scale work in on-going Year 2.
Publications
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Baimatova, N., B. Kenessov, J.A. Koziel, L. Carlsen, M. Bektassov, O. Demyanenko. 2016. Simple and accurate quantification of BTEX in ambient air by SPME and GC-MS. Talanta, 154, 46-52. doi:10.1016/j.talanta.2016.03.050.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Maurer, D., J.A. Koziel, J.D. Harmon, S.J. Hoff, A.M. Rieck-Hinz, D.S Andersen. 2016. Summary of performance data for technologies to control gaseous, odor, and particulate emissions from livestock operations: Air Management Practices Assessment Tool (AMPAT). Data in Brief, 7, 1413-1429. doi: 10.1016/j.dib.2016.03.070.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Soso, S.B., J.A. Koziel. 2016. Analysis of odorants in marking fluid of Siberian tiger (Panthera tigris altaica) using simultaneous sensory and chemical analysis with headspace solid-phase microextraction and multidimensional gas chromatography-mass spectrometry-olfactometry. Molecules, 21(7), 834; doi: 10.3390/molecules21070834834.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2016
Citation:
Maurer, D., J.A. Koziel, K. Kalus, D.S. Andersen, S. Opalinski. 2016. Pilot-scale testing of biochar for swine manure treatment and mitigation of odorous VOCs, ammonia, hydrogen sulphide and greenhouse gas emissions. In the proceedings of the Livestock Waste 2016 Conference, Galway, Ireland, August, 2016.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2016
Citation:
Maurer, D., J.A. Koziel, K. Bruning. 2016. Field scale measurement of greenhouse gas emissions from land applied swine manure. In the proceedings of the Livestock Waste 2016 Conference, Galway, Ireland, August, 2016.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2016
Citation:
Kalus, K, S. Opalinski, D. Maurer, S. Rice, J.A. Koziel, M. Korczy?ski, Z. Dobrzanski, R. Ko?acz, B.
Gutarowska. 2016. Odour reducing microbial-mineral additive for poultry manure treatment. In the proceedings of the Livestock Waste 2016 Conference, Galway, Ireland, August, 2016.
- Type:
Conference Papers and Presentations
Status:
Other
Year Published:
2016
Citation:
Kenessov, B., N. Baimatova, D. Orazbayeva, J.A. Koziel. 2016. Accurate quantification of time-weighted average concentrations of BTEX by SPME and GC-MS. In the proceedings of the ExTech 2016 18th International Symposium of Advances in Extraction Technologies & 22nd International Symposium of Separation Sciences, Torun, Poland, June 2016.
- Type:
Conference Papers and Presentations
Status:
Other
Year Published:
2016
Citation:
Maurer, D., C.K. Ellis, T. Thacker, S. Rice, J.A. Koziel. 2016. Screening of microbial volatile organic compounds for detection of disease in cattle: development of lab-scale method. In proceedings of the ExTech 2016 18th International Symposium of Advances in Extraction Technologies & 22nd International Symposium of Separation Sciences, Torun, Poland, June 2016.
- Type:
Conference Papers and Presentations
Status:
Other
Year Published:
2016
Citation:
Bokova, A., C. Diaz, J.A. Koziel, M. McGinley, J. Barclay. 2016. Overview of the odour legislation in selected countries of Europe, North America, and Oceania. In Proceedings of the 1st International Odour Conference (MKO 2016), Gdansk, Poland, April 2016.
- Type:
Conference Papers and Presentations
Status:
Other
Year Published:
2016
Citation:
Koziel, J.A., D. Maurer, J. Harmon, S. Hoff, A. Rieck-Hinz., D. Andersen. 2016. Air Management Practices Assessment Tool (AMPAT): On-line resource for odors and air quality associated with U.S. livestock production systems. In proceedings of the 1st International Odour Conference (MKO 2016), Gdansk, Poland, April 2016.
- Type:
Conference Papers and Presentations
Status:
Other
Year Published:
2016
Citation:
Cai, L., J.A. Koziel, M. Dharmadhikari, J (Hans) van Leeuwen. 2016. Method for rapid quantification of trans-resveratrol in red wine by solid-phase microextraction with on-fiber derivatization and multidimensional gas chromatography mass spectrometry. In the proceedings of the 1st International Conference Man-Food-Health, Wroclaw, Poland, March, 2016.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Cai, L., J.A. Koziel, S. Zhang, A.J. Heber, E.L. Cortus, D.B. Parker, S.J. Hoff, G. Sun, K.Y. Heathcote, L.D. Jacobson, N. Akdeniz, B.P. Hetchler, S.D. Bereznicki, E.A. Caraway, T.T. Lim. 2015. Odor and odorous chemical emissions from animal buildings: Part 3 chemical emissions. Transactions of ASABE. 58(5), 1333-1347. doi.10.13031/trans.58.11199.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Zhang, S., J.A. Koziel, L. Cai, S.J. Hoff, K. Heathcote, L. Chen, L. Jacobson, N. Akdeniz, B. Hetchler, D.B. Parker, E. Caraway, A.J. Heber, S. Bereznicki. 2015. Odor and odorous chemical emissions from animal buildings: Part 5 correlations between odor intensities and chemical concentrations (GC-MS/O). Transactions of ASABE, 58(5) 1349-1359. doi.10.13031/2013.32645.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Yang, X., W. Zhu, J.A. Koziel, L. Cai, W. Jenks, Y. Laor, H. van Leeuwen, S. J. Hoff. 2015. Improved quantification of livestock associated odorous volatile organic compounds in a standard flow-through system using solid-phase microextraction and gas chromatography - mass spectrometry. Journal of Chromatography A, 1414, 31-40.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Yegemova, S., M.A. Derbissalin, B.N. Kenessov, J.A. Koziel. 2015. Quantitation of phenol in soil using solid-phase microextraction, gas chromatography-mass spectrometry and standard addition. Chemical Bulletin of Kazakh National University, 4, 4-12. doi:10.15328/cb672
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Zhu, W., J.A. Koziel, L. Cai, D. Wright, F. Kuhrt. 2015. Testing odorants recovery from a novel metalized fluorinated ethylene propylene gas sampling bag. Journal of the Air & Waste Association, 65(12), 1434-1445.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Rice, S., J.A. Koziel. 2015. Characterizing the smell of marijuana by odor impact of volatile compounds: An application of simultaneous chemical and sensory analysis. PLoS One, 10(12): e0144160. doi: 10.1371/journal.pone.0144160.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Rice, S., J.A. Koziel. 2015. Odor impact of volatiles emitted from marijuana, cocaine, heroin and their surrogate scents. Data in Brief, 5, 653-706.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Rice, S., J.A. Koziel. 2015. The relationship between chemical concentration and odor activity value explains the inconsistency in making a comprehensive surrogate scent training tool representative of illicit drugs. Forensic Science International, 257, 257-270.
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Onuki, S., J.A. Koziel, W.S. Jenks, L. Cai, S. Rice, J.H. van Leeuwen. 2015. Ethanol purification with ozonation, activated carbon adsorption, and gas stripping. Separation and Purification Technology, 151, 165-171.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Glanville, T.D., H.K. Ahn, N. Akdeniz, B.P. Crawford, J.A. Koziel. 2016. Performance of a plastic- wrapped composting system for biosecure emergency disposal of disease-related swine mortalities. Waste Management, 48, 483-491.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Cai, L., S. Rice, J.A. Koziel, W.S. Jenks, J.H. van Leeuwen. 2016. Further purification of food-grade alcohol to make a congener-free product. Journal of the Institute of Brewing, 122(1), 84-92.
- Type:
Journal Articles
Status:
Published
Year Published:
2016
Citation:
Onuki, S., J.A. Koziel, W.S. Jenks, L. Cai, S. Rice, J.H. van Leeuwen. 2016. Optimization of extraction parameters for quantification of fermentation volatile by-products in industrial ethanol with solid-phase microextraction and gas chromatography. Journal of the Institute of Brewing, 122(1), 102-109.
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Progress 11/06/14 to 09/30/15
Outputs
Target Audience:Livestock industry, regulatory agencies, researchers, students and public. Changes/Problems:
Nothing Reported
What opportunities for training and professional development has the project provided? U.S. Fulbright Scholar assignment (Jacek Koziel) (October 1, 2015 - June 30, 2016) at the Wroclaw University of Environmental and Life Sciences. This assignment is a direct result of existing, study abroad trips program to Poland that focuses on livestock production, sustainability, environment and technology running each year since 2011 and serving Iowa State University students. Agriculture Study Abroad program to Poland had a record participation of students this year (15 students). The trip is focused on collaborative project work with students in Poland focused on comparative projects related to agriculture, environment, sustainability and technology in Poland (EU) and Iowa (US). How have the results been disseminated to communities of interest? Extension website (Scientific Literature Database - a comprehensive literature review of livestock odor and air quality mitigation technologies have been posted as integral part of the Improvement to Air Management Practices Assessment Tool (AMPAT) website). Oral presentations (2) at the Annual International Meeting of the American Society of Agricultural and Biological Engineers, New Orleans, LA, July 2015. Invited presentation to the Iowa Department of Natural Resources focused on mitigation of livestock odor and air quality (February 2015). What do you plan to do during the next reporting period to accomplish the goals? U.S. Fulbright Scholar assignment (Jacek Koziel) (October 1, 2015 - June 30, 2016) at the Wroclaw University of Environmental and Life Sciences focused on strengthening STEM collaborations and developing additional opportunities to study abroad programs (exchanges and internships). Publications of scholarly research focused on livestock odor mitigation and air quality. Research focused on development and testing of livestock odor mitigation technologies for improvement of air quality.
Impacts
What was accomplished under these goals?
Overall impact statement: Major progress was made in several areas including (1) most comprehensive scientific literature database focused on mitigation of odor and air quality at livestock operations was posted on ISU Extension and Outreach website (http://www.agronext.iastate.edu/ampat/database/homepage.html), (2) publications focused on livestock odor and air quality mitigation, (3) record number of students participated in the Agriculture Study Abroad program to Poland, and (4) major NIFA AFRI Food Security proposal was submitted by the S-1032 committee (Jacek Koziel is one of co-PIs). Objective 1) Engage collaborators from the needed broad range of disciplines, institutions, and stakeholder groups to catalyze conceptual and quantitative synthesis, collaboration, and data sharing. Collaborators from range of disciplines, institutions and stakeholders were engaged to develop and submit a $4M project proposal to USDA-AFRI-Food Security program. The proposal was focused on "Integrated use of system-dynamics tools, standardized data-sharing mechanisms, and professional-development strategies to build a research network centered on triple-bottom-line sustainability of animal production systems." Collaborative international projects were created by students from Iowa State University and participating universities in Poland as part of Agriculture Study Abroad trip in May 2015. Projects were presented during two Polish-American Workshops. Conference presentation of a paper summarizing this 5-year-old program was made. A manuscript is being prepared for peer-review and publication. Objective 2) Discover (or reveal), substantiate, and interpret the broader impacts of component-level modifications to animal-production systems. The most comprehensive scientific literature database focused on mitigation of odor and air quality at livestock operations was posted on ISU Extension and Outreach website (http://www.agronext.iastate.edu/ampat/database/homepage.html). More than 250 papers were reviewed and summarized in easy to access form. It was discovered that an overwhelming majority of odor and air quality mitigation technologies have not been tested in the field. Only a few studies attempted to comprehensively assess the effectiveness of a technology for all major air pollutants of concern. The majority of odor mitigation work was focused on swine, with the number of papers greater than for beef cattle, dairy cattle, and poultry combined. Publications focused on livestock odor and air quality mitigation were published as journal articles (1 published, 3 awaiting publication, 1 submitted, 2 conference papers and presentations, and one website).
Publications
- Type:
Journal Articles
Status:
Published
Year Published:
2015
Citation:
Yang, X., W. Zhu, J.A. Koziel, L. Cai, W. Jenks, Y. Laor, H. van Leeuwen, S. J. Hoff. 2015. Improved quantification of livestock associated odorous volatile organic compounds in a standard flow-through system using solid-phase microextraction and gas chromatography - mass spectrometry. Journal of Chromatography A, 1414, 31-40.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2015
Citation:
Koziel, J.A., D. Andersen, J. Harmon, S. Hoff, D. Maurer, A. Rieck-Hinz. 2015. Improvement to Air Management Practices Assessment Tool (AMPAT): Scientific Literature Database. ASABE paper #152190993 in the proceedings of the ASABE Annual International Meeting, New Orleans, LA, July, 2015.
- Type:
Conference Papers and Presentations
Status:
Published
Year Published:
2015
Citation:
Koziel, J.A. Enhancing student learning through Technology Travel Course: Ag Study Abroad program to Poland. ASABE paper # 152190399 in the proceedings of the ASABE Annual International Meeting, New Orleans, LA, July, 2015.
- Type:
Websites
Status:
Published
Year Published:
2015
Citation:
http://www.agronext.iastate.edu/ampat/database/homepage.html (Iowa State University, Extension and Outreach, 2015, Scientific Literature Database, Improvement to Air Management Practices Assessment Tool (AMPAT).
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