$1 billion in damage annually. In extreme cases, entire fields are intentionally destroyed or abandoned. Infestation of crop commodities can also significantly reduce the storage life and nutrition quality. Furthermore, mosquito-borne diseases such as equine encephalitis, dog heartworm, and West Nile virus continue to be a growing problem each year in US and worldwide. Some of the most effective control measures have been insecticides. Unfortunately, insecticides have non-target effects that are often compounded by environmental persistence. Unlike most insecticides, dsRNA's are biocompatible, biodegradable, environmentally benign, and has the potential of being a selective insecticide that interferes with genes critical to insect survival. More importantly, the phenomenal potential of RNAi is that it is both specific for the gene of interest, and for the organism being targeted. Thus, dsRNA would offer extremely high pest specificity without the downsides of human and environmental risk. Encapsulation of dsRNA in biodegradable polymers (e.g. PLA) will not only prevent premature degradation of the dsRNA, but will also provide a stable release platform allowing a gradual and steady release of the insecticide. By incorporating UV-blockers, such as titanium dioxide, we will be able to further enhance the stability of the dsRNA allowing it to effectively deliver the insecticide for a greater duration compared to current commercially available pesticides. Upon translation to market, the technology will benefit farmers and non-farmers alike because it will offer a pest-specific insecticide with virtually no adverse human or environmental effects. It will also benefit the economy, including the Biopesticide Industry Alliance, a consortium of businesses dedicated to fostering adoption of biopesticide technology. Upon demonstrating the technology, several national and international research programs could further develop it to benefit a broader audience. These programs include USDA's new Research and Education for Improved Pest Control which encourages development and implementation of IPM while reducing human and environmental risks. Additionally, organizations such as NIH, WHO and the Gates Foundation could be interested to help globally reduce the spread of insect-born human diseases.' />
Source: CORNELL UNIVERSITY submitted to NRP
DEVELOPMENT OF SPECIES SPECIFIC AND ENVIRONMENTALLY SAFE BIO-INSECTICIDES
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0230881
Grant No.
(N/A)
Cumulative Award Amt.
(N/A)
Proposal No.
(N/A)
Multistate No.
(N/A)
Project Start Date
Oct 1, 2012
Project End Date
Sep 30, 2015
Grant Year
(N/A)
Program Code
[(N/A)]- (N/A)
Recipient Organization
CORNELL UNIVERSITY
(N/A)
ITHACA,NY 14853
Performing Department
Biological & Environmental Engineering
Non Technical Summary
Insects are major pests of crops and act as vectors transporting diseases to animals and humans causing billions of dollars' worth of losses. In the US, the armyworm, diamondback moth, and red flour beetle, each cause > $1 billion in damage annually. In extreme cases, entire fields are intentionally destroyed or abandoned. Infestation of crop commodities can also significantly reduce the storage life and nutrition quality. Furthermore, mosquito-borne diseases such as equine encephalitis, dog heartworm, and West Nile virus continue to be a growing problem each year in US and worldwide. Some of the most effective control measures have been insecticides. Unfortunately, insecticides have non-target effects that are often compounded by environmental persistence. Unlike most insecticides, dsRNA's are biocompatible, biodegradable, environmentally benign, and has the potential of being a selective insecticide that interferes with genes critical to insect survival. More importantly, the phenomenal potential of RNAi is that it is both specific for the gene of interest, and for the organism being targeted. Thus, dsRNA would offer extremely high pest specificity without the downsides of human and environmental risk. Encapsulation of dsRNA in biodegradable polymers (e.g. PLA) will not only prevent premature degradation of the dsRNA, but will also provide a stable release platform allowing a gradual and steady release of the insecticide. By incorporating UV-blockers, such as titanium dioxide, we will be able to further enhance the stability of the dsRNA allowing it to effectively deliver the insecticide for a greater duration compared to current commercially available pesticides. Upon translation to market, the technology will benefit farmers and non-farmers alike because it will offer a pest-specific insecticide with virtually no adverse human or environmental effects. It will also benefit the economy, including the Biopesticide Industry Alliance, a consortium of businesses dedicated to fostering adoption of biopesticide technology. Upon demonstrating the technology, several national and international research programs could further develop it to benefit a broader audience. These programs include USDA's new Research and Education for Improved Pest Control which encourages development and implementation of IPM while reducing human and environmental risks. Additionally, organizations such as NIH, WHO and the Gates Foundation could be interested to help globally reduce the spread of insect-born human diseases.
Animal Health Component
(N/A)
Research Effort Categories
Basic
(N/A)
Applied
(N/A)
Developmental
(N/A)
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
4035220202025%
4035220113025%
7235220202025%
7235220113025%
Goals / Objectives
Our goal is to engineer an effective and economic double-stranded RNA (dsRNA) bio-insecticide formulation that is specific to a target pest and can be designed to provide sustained and controlled released of an environmentally friendly pesticide alternative to replace conventional broad-spectrum insecticides. The process of maintaining populations of the target insects in check offers the potential to produce more commodities that can supply our ever growing need for food at national and world levels. In addition, the ability to control the release rate would reduce the treatment costs since fewer pesticide applications would be required. The encapsulated dsRNA would have a slow and constant release, in contrast to an initial release spike followed by a greatly diminished release that is typically seen from conventional pesticide applications. Unlike most insecticides, dsRNA's, which operate by interfering with gene transcription (termed RNA interference or RNAi), are biocompatible, biodegradable and environmentally benign. More importantly, the phenomenal potential of RNAi is that it is both specific for the gene of interest, and for the organism being targeted. Furthermore, by developing methods to target pathogen carriers such as mosquitoes, we can reduce the potential spread of disease and at the same time have an environmentally friendly reduced-risk insecticide that will not adversely affect higher members of the food chain, such as fish, birds, and humans. The following objectives have been proposed to achieve our overall goal: 1) Use drug delivery technologies to encapsulate dsRNA. 2) Determine whether biopolymer encapsulated dsRNA can deliver a toxic dose to insects. 3) Optimize biopolymer formulations to impart robust stability to dsRNA. 4) Identify other dsRNAs that target Colorado potato beetle critical genes for suppression. 5) Test new candidate UV-stabilized biopolymer formulations and dsRNA's under a wide range of environmental conditions. Upon the conclusion of this project we envision having developed a novel, economic, environmentally friendly, and target specific insecticide and delivery system. This system will be able to be mass marketed with a wide range of applications for targeting insects that are responsible for crop destruction to insects that are capable of transporting pathogens to humans and animals.
Project Methods
The methods in which we will implement our project design are as follows: 1) Since dsRNA's are highly unstable in the environment and need to be protected before being applied, we will encapsulate the dsRNA in biodegradable polymers, e.g. poly-lactic acid (PLA), using a double emulsion (water/oil/water) method. PLA, which is bulk-produced from renewable resources and commercially available at reasonable cost, is UV-stable, biodegradable, and have been employed as an FDA-approved medical drug delivery vehicle for human consumption. The biopolymer will be dissolved in methylene chloride first and dsRNA added to the solution drop-wise; the mixture is then cooled and sonicated. After a double-emulsion forms, it will be purified by centrifuging and freeze-dried. The formulations will then be exposed to UV radiation for varying durations before bioassays with Colorado Potato Beetles (CPB) to determine the amount of dsRNA stabilization. dsRNA that is specific for CPB, vATPaseE (vacuolar ATP synthase subunit E) and Sec23 (a transport protein) will be encapsulated into PLA in a sprayable microsphere format. 2) We will conduct bioassays by feeding PLA-encapsulated dsRNA to CPB larvae. Larval mortality will be assessed daily and compared to controls. We will also compare the relative amount of vATPaseE and Sec23 transcripts using quantitative RT-PCR in larvae that were fed leaves + water (control), compared to leaves treated with dsRNA and held for 0, 2 and 4 days before being presented to larvae. 3) Concentrations of dsRNA will be varied to test for dose response and, if needed, formulations will be further engineered for UV stability by the addition of UV-protectant compounds, e.g. titanium dioxide. 4) Novel dsRNA's will be identified for efficacy of beetle gene suppression. 5) Testing of novel formulations and dsRNA's under diverse environmental conditions. The primary metric is dsRNA stabilized for up to 3 days UV exposure. We will measure beetle mortality and quantify gene suppression as a function of irradiation duration. Secondary metrics are dissemination and publication of results so that interested researchers are stimulated to consider this technique for stabilizing other unstable pesticides. Initially, the outcomes will be extensively quantified in a controlled laboratory environment, followed by wider environmental conditions.

Progress 10/01/12 to 09/30/15

Outputs
Target Audience:Target audiences included undergraduate students, graduate students, postdocs, and technicians that are engaged in and/or interested in developing bioinsecsides with biocompatible materials. They also included industry practioners and international colleagues and collaborators. Efforts including research and development, educational activities, translational and attempted commercialization, and international collaboration. Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided?We have educated a number of graduate students and postdocs under this grant. They obtained solid and broad training in a diverse discipline including molecular biology, RNA biology, bioengineering, controlled release, materials engineering, etc. How have the results been disseminated to communities of interest?Results have been disseminated to professional communities in the agriculture fields through invited talks, international conferences, and professional networking. Intellectual property disclosures were filed and Industry partners were informed through Cornell's technology transfer office. National and international colleagues were informed and general collaboration was established. What do you plan to do during the next reporting period to accomplish the goals? Nothing Reported

Impacts
What was accomplished under these goals? Insects are major pests of crops and vectors of diseases of animals and humans throughout the world, causing billions of dollars' worth of losses. In the US alone, the armyworm, diamondback moth, and red flour beetle, each cause > $1 billion in damage annually. In extreme cases, entire fields must be intentionally destroyed or abandoned. Infestation of crop commodities can also significantly reduce the storage life and nutrition quality. Furthermore, mosquito-borne diseases such as equine encephalitis, dog heartworm, West Nile virus and more recently the Zika virus have become a growing problem each year in NY and elsewhere. Some of the most effective control measures have been insecticides. Unfortunately, insecticides have non-target effects that are often compounded by environmental persistence. Recently, double-stranded RNA (dsRNA) has been used as a new tool study the transcription of genes. Unlike most insecticides, dsRNAs are biocompatible, biodegradable and environmentally benign. More importantly, the phenomenal potential of RNAi is that it is both specific for the gene of interest, and for the organism being targeted. Thus, dsRNA would offer extremely high pest specificity without the downsides of human and environmental risk. Previously we have used dsRNA to impart stability to bioallethrin, a model unstable insecticide. This grant extended that work providing a greener bio pesticide to target an important problem in agriculture. At the same time, we have also developed a practical delivery system that can protect nucleic acids in general and RNA in particular. The system consist of nanoclay. More specifically, we 1) employed human drug delivery technologies to agriculture by encapsulating dsRNA in various biocompatible materials. We also 2) determine whether the encapsulated dsRNA can deliver a toxic dose to insects. We 3) further optimized formulations to impart robust stability to dsRNA and 4) identified other dsRNAs targeting Colorado potato beetle critical genes for suppression. Finally 5) we tested new candidate UV-stabilized formulations and dsRNA's under a wide range of environmental conditions. We have accomplished most of the proposed major goals including development, characterization, and optimization of the biocompatible and environmental friendly materials for encapsulation of bioinsectcide. More specifically, we have verified the important roles of dsRNA in RNA interference as a bioinsectcide. We have successfully used (human) drug delivery technologies to encapsulate and protect dsRNA. Using a variety environmental conditions including different UV dose, we tested new formulations of UV-stabilized biopolymers. We have also developed a new method to mass produce dsRNA that would be very useful in future translational efforts. The impact lies in the fact that we developed an environmental friendly and specific bioincectsides to control insects. We also discovered that nanoclay would be an ideal material for broader agriculture applications. We have attempted to license our technology to certain industry partners in order to translate our research to commercial products.

Publications


    Progress 10/01/13 to 09/30/14

    Outputs
    Target Audience: Students including postdocs, graduate students, and undergraduate students who have been trained in various settings. Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided? Mentoring, through various laboratory and class-room settings, students including postdocs, graduate students, and undergraduate students. How have the results been disseminated to communities of interest? Through professional conferences and reports. What do you plan to do during the next reporting period to accomplish the goals? Nothing Reported

    Impacts
    What was accomplished under these goals? An environmental friendly delivery system using biopolymerer provides a sustainable approach to deliver pestcides. In addition, bio-secticide formulation further replaces the conventional broad-spectrum insecticides and thus is believed less dentrimental to the environment. We have tested the dsRNA as bio-insecticide and its specificity and efficacy, along with delivery system that is inspired by biocompatible polymers used in the biomedical settings. In addition, we explored the ways to reduce the cost of the biopolymer as well as new routes to synthesize large quantities of dsRNA. We also tested UV-stablization properties of these polymers.

    Publications


      Progress 10/01/12 to 09/30/13

      Outputs
      Target Audience: Nothing Reported Changes/Problems: Nothing Reported What opportunities for training and professional development has the project provided? This project has involved several graduate and undergraduate students in working with dsRNA and also biopolymer. More specifically, students have been trained in thedouble emulsion method to prepare microspheres and also in characterization techniques including scanning electron microscopy, imaging processing, and dynamic light scattering for size determination. How have the results been disseminated to communities of interest? Nothing Reported What do you plan to do during the next reporting period to accomplish the goals? We will continue to work on dsRNA as a pesticide and use biopolymer to protect dsRNA and controlits release.

      Impacts
      What was accomplished under these goals? We are in the process of verifying important roles of dsRNA in RNA interference as a biopesticide. We are using drug delivery technologies to encapsulate and protect dsRNA. We have also started to test the new UV-stablizable biopolymer formulations under a various environmental conditions. Optimization of biopolymer formulations to impart robust stability to dsRNA is also underway.

      Publications