Source: Multiform Harvest Inc. submitted to NRP
RESEARCH AND DEVELOPMENT LEADING TO COMMERCIAL FEED AND FERTILIZER PRODUCTS MADE FROM STRUVITE EXTRACTED FROM DAIRY WASTEWATER.
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0230014
Grant No.
2012-33610-20014
Cumulative Award Amt.
$448,947.00
Proposal No.
2012-02151
Multistate No.
(N/A)
Project Start Date
Sep 1, 2012
Project End Date
Aug 31, 2014
Grant Year
2012
Program Code
[8.4]- Air, Water and Soils
Recipient Organization
Multiform Harvest Inc.
3109 South Frontenac St.
Seattle,WA 98108
Performing Department
(N/A)
Non Technical Summary
Multiform Harvest Inc. ("Multiform") produces the fertilizer struvite, which is magnesium ammonium phosphate hexahydrate. Multiform produces the struvite by extracting it from wastewaters containing excess phosphorus. Multiform sells into two markets: 1) wastewater generators who need to reduce the phosphorus content of the wastewater; and 2) consumers of the nutrients provided by the struvite produced at the wastewater generator sites. The SBIR project focuses on the second market (nutrient consumers). This project, of which the phase I is complete, seeks to further improve the economics of the struvite extraction technology, thus accelerating its adoption, by developing means to convert the crude struvite produced by the extraction process to a higher-value, specialized product. The activities planned for phase II of the project aim to work out continuous, commercially useful processes and apparatuses to produce the high-value products (pellets and formed products such as spikes and tablets) for which the first phase provided product specifications and laboratory-scale, batch type means of producing. Specifically, the technical objectives are (1) Verify market information achieved through Phase I research for five targeted products through direct consultation with buyers. Present upgraded struvite products to buyers and verify that they are ready for commercial sale at a known value; (2) Confirm that struvite products meet buyer nutritional and performance specifications through greenhouse growing trial; (3) Identify potential processes for commercial-scale continuous drying and forming, and identify the necessary struvite conditions and formulas; (4) Develop and monitor continuous manufacturing processes for pelletizing and forming products at laboratory scale; (5) Design and build prototype a manufacturing system capable of drying and forming struvite into one or more target products; and (6) Determine capital and production costs for full operating system, and compare with market data for profit estimate for one or more systems.
Animal Health Component
50%
Research Effort Categories
Basic
(N/A)
Applied
50%
Developmental
50%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
1022410106050%
1120320107050%
Goals / Objectives
The goal of this project, which is a Phase 2 project, is to upgrade struvite, which is a high-nutrient by-product of Multiform's technology for reducing excessive phosphate in wastewater, to a higher-value product. The objectives are definition of product specifications for particular higher-value applications, development of means to transform the product to meet those specifications (including pelletizing, shaping, sizing, and blending), and testing of product made to those specifications. Multiform's Phase 1 research was initiated on the assumption that struvite, would compact in a die pelletizer if the right combination of dies, bonding agents, pressure, and throughput could be identified. Compaction was desired for upgrading the by-product into a more valuable nutrient product. After several test batches were processed in a small pelletizing plant operated by a commercial feed and fertilizer distributor, we discovered that the material would not cohere sufficiently to produce a marketable product. A better means of upgrading, chemical forming, was then developed by Multiform. For the two products originally attempted through die pelletizing (turf broadcasting pellets and pop-up fertilizer), values and costs are moderate, but acceptable. Multiform does not believe die pelletizing can be easily combined with chemical forming because the latter requires several minutes for chemical transformation, while in the former, each pellet is created in a fraction of a second. Pelletizing techniques that do offer potential for combining with chemical drying are those in which pellets are built up slowly over several minutes, such as pan, disk, and drum pelletizing. These are more expensive than die pelletizing, but Multiform's market research indicates that specialized struvite product prices will be high enough to more than cover the cost of these other techniques. The Phase 2 research proposed here is the logical followup to our laboratory experiments that showed the technical feasibility of rendering struvite into five target forms. It is designed to discover a mechanical commercial process (or processes) that can shape struvite while it exists in either a dried but otherwise unimproved state or in a chemically hardened state. The research probes two potential pathways (referred to in "Identification of the Problem and Opportunity," above) by experimenting with existing technology capable of producing "mid-value" products (pop-up fertilizers and turf pellets), and developing a new process that could produce the higher value products. The investigation also includes greenhouse research on potted plants to better define struvite's nutritional performance, and market analysis to test the market value of all products. Regarding expected outputs of the project, meeting the above objectives will place Multiform Harvest Inc. into position to begin commercial marketing of the selected high-value struvite-based nutrient product(s). The selected product(s) will have market demand well-characterized and production process and costs well-defined.
Project Methods
The efforts on the project will be organized according to its six objectives, each with several tasks (the final task in each objective generally including an evaluation): Technical Objective 1: Verify market information achieved through Phase I research. Task 1: Consult with Kenneth Tornberg, Wolfkill Feed and Fertilizer, and other associated experts to identify buyers of five target products. Task 2: Consult directly with buyers to obtain potential price, required product specifications, and information on competing products. Task 3: Integrate struvite performance data gained through WSU greenhouse growing trials into a comprehensive product report for potential buyers. Task 4: Re-visit potential buyers and present struvite products. Confirm product market value as an evaluation of whether the market information has been properly interpreted. Technical Objective 2: Confirm that struvite products meet buyer nutritional and performance specifications through greenhouse growing trial. Task 1: Compare the performance of mined triple superphosphate with two different struvite formulations. Task 2: Measure plant growth in response to varying struvite formulations, rates and methods of application. Task 3: Evaluate optimal struvite treatments for their effect on nutrient content. This will serve as an evaluation of whether the products meet buyer specifications. Technical Objective 3: Identify potential processes for commercial-scale continuous drying and forming, and identify the necessary struvite conditions and formulas. Task 1: Consult to confirm process. Task 2: Eevaluate compaction with a Tinius-Olsen Universal Testing Machine to get precise data. Task 3: Apply process. Physical properties of the granular product will be used to evaluate success of the binders and methods. Technical Objective 4: Develop and monitor continuous manufacturing processes for pelletizing and forming products at laboratory scale. Task 1: Consult with project partners to evaluate whether a pan pelletizer is capable of producing a marketable product. Task 2: Multiform and and its partners will design and perform tests with tabletop prototypes of potential drying and shaping devices. Technical Objective 5: Design and build prototype manufacturing system capable of drying and forming struvite into one or more target products. Task 1: Multiform will produce preliminary design for commercial-scale system. Task 2: Identify machining companies with expertise in manufacturing technology, select one, and initiate agreement. Task 3: Arrange for facilities at the Puyallup Center to assemble and test the prototype process. Task 4: Assemble prototype, perform initial runs, and evaluate performance. To evaluate this output, products must be presentable to potential buyers. Technical Objective 6: Determine capital and production costs for full-scale operating system. Task 1: Present finished product samples to buyers and seek commitment for purchase. Task 2: Arrive at net present value estimates for commercial manufacturing facility, present to potential investors, and seek their evaluation. Task 3: Create marketing and business plan.

Progress 09/01/12 to 08/31/14

Outputs
Target Audience: Target audiences were primarily growers who buy fertilizer products, and also buyers of fertilizer products who are NOT growers. This last category includes re-sellers of fertilizer, such as wholesalers and blenders. A secondary audience was wastewater sites who potentially can use our wastewater technology, which generates fertilizer products in their unprocessed state. Changes/Problems: One major change in approach was made. The original workplan called for development of processing techniques to produce the higher-value struvite products to be done under a subcontract with WSU (Washington State University). Further consideration of WSU's capabilities revealed only marginal expertise and facilities in this specific area, and coincidentally, discussions with FEECO International of Green Bay, Wisconsin showed advanced knowledge and ideal facilities for this work. Therefore, after gaining agreement from both WSU and FEECO, and gaining approval also from the SBIR staff, the subcontracted work was shifted from WSU to FEECO. Other work subcontracted to WSU remained in place with WSU. What opportunities for training and professional development has the project provided? Nothing Reported How have the results been disseminated to communities of interest? Nothing Reported What do you plan to do during the next reporting period to accomplish the goals? Nothing Reported

Impacts
What was accomplished under these goals? Summary of Accomplishments Manufacture of spherical struvite pellets of marketable size and hardness at commercial scale. Formation and testing of struvite spikes suitable for home gardening systems using patented chemical drying technique. Completion of nursery growing trials by Washington State University demonstrating that struvite is a drop-in replacement for conventional phosphate fertilizers. Completion of research by the Agricultural Research Service and Washington State University testing struvite with field crops. Design and implementation of a processing system rendering struvite into a basic, saleable form for turf-grass fertilizer companies. Testing and Confirmation of commercial-scale drying process and request for proposals submitted to equipment manufacturers. Purchase Agreement with a fertilizer company and processing of struvite product. Assessment by national experts of struvite’s potential advantages in the agricultural sector, most notably as a pop-up fertilizer for row crops, and identification of need for further research. Multiform has successfully produced marketable struvite pellets at a commercial scale in conjunction with a major industrial processing company, while also identifying vendors of drying and granulating equipment that will render struvite into a marketable product for turf-grass fertilizer companies. Both the pellets and granulated product have been officially inspected by potential buyers and have met all required specifications. Washington State University expanded its growing trials beyond the greenhouse tests performed last year, applying struvite to nursery starts grown outdoors. The results authoritatively demonstrated that struvite stimulates plant growth as well as conventional phosphorus fertilizers and that it can achieve these results even when applied in very small amounts directly to plant roots. Based on this and other crop research conducted by Multiform and its agricultural marketing consultant in Phase 1, Multiform submitted an inquiry to leading researchers on “pop-up” and “starter” fertilizers, compiling a list of nutrients that could be added to struvite to tailor its application to specific crops, such as corn and soybeans, and research questions to focus on in the future. At completion of this SBIR phase 2 grant, Multiform is preparing to install a drying and processing system at its Boise facility, enter a service agreement with an industrial manufacturer to produce high-value pellets, and build a fourth struvite extraction facility in Green Bay, WI. Leveraging the successes achieved during this SBIR-supported project, Multiform has received during this project $575,000 in further investment agreements (debt and equity) from five investors. (Multiform had previously received over $500,000 in earlier investments, stemming from investor enthusiasm resulting from successes demonstrated in earlier SBIR projects at Multiform.) The current funds are intended to bridge to a larger investment, which Multiform expects will be its last need for external funds before it becomes cash-flow-positive. Multiform is now in advanced discussions with two enterprises (one being a venture capital group and the other being a large corporation related to the agriculture industry) for provision of this final, larger investment. Conclusion This project, funded by the SBIR program, has moved Multiform Harvest Inc. forward in four major ways. First, through the work needed to prepare its un-processed struvite for the upgrading process, it now has a means to dry, de-lump, package and sell (with ready customers) its raw struvite from its three (soon to be four) existing wastewater extraction sites. Second, the project developed a commercially feasible upgraded product (again, with ready customers) consisting of high-quality, round, hard, size-controllable, flowable pellets, with the process to produce it demonstrated at full scale. Third, the work developed means to produce molded products (tablets, spikes, etc.) for additional high-value specialty markets. These latter means have not been demonstrated at commercial scale but can be further developed as Multiform and its market reach expands. Finally, the project’s successes have enabled the enterprise to access $575,000 in capital beyond that reported in earlier communications with the SBIR program and positioned it well in its current negotiations with financiers for a final investment to bridge the enterprise to a cash-flow-positive condition.

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