Source: UNIVERSITY OF VERMONT submitted to NRP
EFFECTS OF SAP PRECONCENTRATION BY REVERSE OSMOSIS ON MAPLE SYRUP CHEMICAL COMPOSITION AND FLAVOR
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0221589
Grant No.
2010-34157-21008
Cumulative Award Amt.
(N/A)
Proposal No.
2010-01450
Multistate No.
(N/A)
Project Start Date
Sep 1, 2010
Project End Date
Aug 31, 2011
Grant Year
2010
Program Code
[BA]- Maple Research, VT
Recipient Organization
UNIVERSITY OF VERMONT
(N/A)
BURLINGTON,VT 05405
Performing Department
Plant Biology
Non Technical Summary
Maple syrup production is an agricultural enterprise that provides a vital source of income and helps maintain viable small farms for thousands of producers throughout the maple producing region of the United States and Canada. It is produced and marketed as a specialty, natural sweetener with unique characteristic flavor and aroma properties that underlie its desirability to consumers and high economic value. Concentration of maple sap by reverse osmosis (RO) is often used to increase the profitability of maple production by reducing the large quantities of fuel and time necessary to concentrate sap to maple syrup density using only the traditional method of heating in maple evaporators. However, there has been some concern expressed that producing syrup from maple sap concentrated by RO might yield negative impacts on the flavor and quality of maple syrup. It is currently unknown whether concentrating maple sap with RO produces changes in sap chemistry that affect the properties of the maple syrup produced. Thus, the objective of the proposed work is to determine whether the chemical composition or flavor of syrup produced from unconcentrated maple sap differs significantly from that of syrup produced from the same sap that has been concentrated by RO. Experiments will be conducted in which maple syrup is produced simultaneously with unconcentrated maple sap and the same sap that has been concentrated to 8% sugar by RO. The chemical composition and flavor of the syrups will then be analyzed and compared. The results of the study will provide the knowledge necessary to determine whether the use of RO is a means by which producers can increase the profitability of maple syrup production without detriment to the quality of the maple syrup produced. This information will be communicated to producers through presentations at maple industry conferences and articles published in industry and scientific publications.
Animal Health Component
90%
Research Effort Categories
Basic
10%
Applied
90%
Developmental
(N/A)
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
5010680200045%
5012099100045%
5012099309010%
Goals / Objectives
The objective of this project is to determine whether the chemical composition or flavor of maple syrup produced from unconcentrated maple sap differs significantly from that of syrup produced from the same sap that has been preconcentrated by reverse osmosis (RO). This study will provide knowledge necessary to assess whether the use of RO is a means by which maple producers can increase the profitability of maple syrup production without detriment to the quality of the maple syrup produced. This information will be disseminated to maple producers through presentations at maple industry conferences and meetings, and through articles published in maple industry publications. The knowledge will also be shared with the scientific community through an article in a peer-reviewed scientific journal.
Project Methods
To meet the project objective, experiments will be conducted in which maple syrup is produced simultaneously with unconcentrated ('raw') maple sap and the same sap that has been concentrated to 8% sugar by reverse osmosis (RO). Syrup will also be produced simultaneously with a third treatment: a portion of the sap concentrated by RO to 8% will be diluted with water back to raw sap sugar concentration (~2%). The experiments will be conducted at the University of Vermont Proctor Maple Research Center and will be repeated at least five times during the 2011 maple production season. The physiochemical properties (color, pH, and conductivity), chemical composition (inorganic minerals and carbohydrates), and flavor of the syrup produced with each treatment during each repetition of the experiment will be analyzed. The flavor of the syrup samples produced during the experiments will be analyzed by both quantifying the total amount of volatile flavor and aroma compounds in the samples with gas chromatography-mass spectrometry (GC-MS) and by conducting sensory evaluation experiments. For each syrup parameter analyzed, repeated measures analysis of variance procedures will be used to test the null hypothesis that means were equal in the syrup produced simultaneously with the three treatments, and contrasts will be used to conduct any subsequent pairwise comparisons. If significant differences are not detected in chemical composition or flavor of the syrup produced simultaneously from raw sap and the same sap concentrated by RO, it will suggest that preconcentrating sap with RO does not have a significant impact on these syrup properties, and thus provide support that RO is an acceptable tool maple producers can use to increase the efficiency and profitability of maple syrup production. If significant differences are found between the syrups produced from raw and concentrated sap, then comparisons between the syrups produced from raw sap and the diluted RO concentrate will help distinguish whether these differences are more likely the result of changes caused by the RO concentration process itself, or rather from the different lengths of time the treatments are processed thermally. The knowledge acquired from this study will be disseminated to maple producers through presentations at maple industry conferences and meetings, and through articles published in maple industry publications. When available, exit surveys of conference participants will be used to help assess the impact of the information on producer knowledge or decision-making plans. A manuscript will also be submitted for publication in a peer-reviewed scientific journal to contribute the information obtained to the general body of scientific knowledge.

Progress 09/01/10 to 08/31/11

Outputs
OUTPUTS: Maple syrup production is an agricultural enterprise that provides a vital source of income and helps maintain viable small farms for thousands of producers throughout the maple producing region of the United States and Canada. It is produced and marketed as a specialty, natural sweetener with unique characteristic flavor and aroma properties that underlie its desirability to consumers and high economic value. Preconcentration of maple sap by reverse osmosis (RO) is often used to increase the profitability of maple production by reducing the large quantities of fuel and time necessary to concentrate sap to maple syrup density using only thermal evaporation. However, it is currently unknown whether concentrating maple sap with RO produces changes in sap chemistry that result in negative impacts on the quality or characteristic properties of the maple syrup produced. Thus, the objective of the proposed work was to determine whether the chemical composition or flavor of syrup produced from unconcentrated maple sap differs significantly from that of syrup produced from the same sap that has been preconcentrated by RO. We conducted controlled experiments in which maple syrup was produced simultaneously from raw maple sap (2% sugar) and the same sap that had been concentrated to 8% sugar by RO. Six replications of the experiment were conducted during the 2011 maple production season. The physiochemical properties (pH, conductivity, color, and density) and chemical composition (including inorganic minerals, carbohydrates, and volatile flavor and aroma compounds) of the maple syrup produced in the experiments were subsequently analyzed. In addition, sensory evaluation experiments were conducted to evaluate the effects of the treatments on the flavor of the syrup produced. The data collected were then analyzed statistically to determine if significant differences existed in the chemical composition or flavor of syrup produced simultaneously from unconcentrated, raw sap and the same sap concentrated to 8% by RO. The results obtained are being disseminated to maple producers, industry members, scientists, and extension professionals at maple industry meetings and conferences throughout the maple producing region of the US. PARTICIPANTS: T.D. Perkins and A. van den Berg served as overall project Co-PI's. As such, they designed the overall project, determined goals, and analyzed and presented results. A. van den Berg oversaw the day-to-day planning and execution of the project, including supervision of employees. B. Stowe and M. Isselhardt provided technical assistance in setting up and executing the experiments. TARGET AUDIENCES: Maple syrup producers are the primary target audience. PROJECT MODIFICATIONS: Not relevant to this project.

Impacts
The results from the experiments conducted indicated that maple syrup produced with unconcentrated sap was significantly darker in color than syrup produced from the same sap concentrated to 8% by RO. However, there were few other significant differences in the properties, chemical composition, or flavor profiles of the syrup produced. In addition, in sensory evaluations panelists were unable to detect a difference in flavor between the syrup produced simultaneously with unconcentrated sap and with the same sap concentrated to 8% by RO. The results indicate that producing syrup with sap concentrated by RO does not have a significant impact on syrup chemical composition or flavor. Maple syrup production is an important agricultural enterprise for thousands of producers in Vermont and throughout the maple producing region of the US and Canada. In many cases maple syrup production supplements other agricultural endeavors, such as dairying, as a vital source of income to help maintain viable, profitable farms. Maple syrup is produced and marketed as a specialty, "natural" sweetener with highly valued characteristic color, aroma, and flavor properties that are the foundation of its desirability and economic value to consumers. Preconcentration of maple sap by RO is used to increase the profitability of maple production by reducing the large quantities of time and fuel necessary to concentrate sap to maple syrup density by the traditional method of thermal evaporation in open-pan style evaporators. However, there has been growing concern that producing syrup from sap concentrated by RO might yield negative impacts on the properties of maple syrup by reducing the length of time sap is processed with heat, when the majority of color, flavor, and aroma compounds in syrup are generated. Because of the enormous potential economic benefit to producers that the use of RO provides, it is critical to establish through rigorous scientific investigation whether this technology can be used without detriment to the quality of maple syrup produced and thus provide producers with a means to increase the profitability and long-term economic sustainability of maple syrup production. The goal of our project was to determine whether the chemical composition or flavor of syrup produced from unconcentrated maple sap differs significantly from that of syrup produced from the same sap that has been preconcentrated by RO to determine if it is an acceptable, effective practice to increase the profitability of maple syrup production operations. Results from the experiments we conducted showed that the quality, composition and flavor of maple syrup made with unconcentrated sap did not differ from syrup made from the same sap concentrated to 8% by RO. These results indicate that RO is a means by which producers can increase the profitability and long-term economic sustainability of maple syrup production without detriment to the quality of the maple syrup produced. This new scientific knowledge will also provide assurance to consumers of the quality of maple syrup they purchase.

Publications

  • No publications reported this period