Source: UNIV OF CONNECTICUT submitted to NRP
BIOENERGY: MEETING RENEWABLE ENERGY NEEDS OF CONNECTICUT
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0214577
Grant No.
2008-34603-19452
Cumulative Award Amt.
(N/A)
Proposal No.
2008-03312
Multistate No.
(N/A)
Project Start Date
Aug 15, 2008
Project End Date
Aug 14, 2010
Grant Year
2008
Program Code
[BB-U]- Bioenergy, CT
Recipient Organization
UNIV OF CONNECTICUT
438 WHITNEY RD EXTENSION UNIT 1133
STORRS,CT 06269
Performing Department
ANIMAL SCIENCE
Non Technical Summary
Connecticut is at the end of the "energy pipeline." Virtually all of its energy must be imported. To reach the goal of reducing Connecticut's dependence on petroleum, to create a basis for an in-state bio-energy industry, and to facilitate achieving the state goal that the EPA requires, we propose a systematic research program on energy from bio-resources. This program has four components: 1) Assessing, mapping, and quantifying biomass feedstocks suitable for Connecticut; 2) Genetic improvement of poplar plants for bioenergy applications; 3) Improvement of economic competitiveness of biodiesel; and 4) Economic impact analysis and outreach. The outcome of the proposed research could help reducing Connecticut's dependence on petroleum, taking advantage of underutilized biomass and bio-energy resources produced in Connecticut, reducing residents' risk of developing air-quality related cancers, asthma, and other respiratory illnesses, improving the state's environment, creating new opportunities for the state's agricultural industry, and facilitating the emergence of a new industrial sector.
Animal Health Component
50%
Research Effort Categories
Basic
40%
Applied
50%
Developmental
10%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
2010620106025%
1230699209025%
5111848202025%
6056199301025%
Goals / Objectives
Objective 1: Assessing, mapping, and quantifying biomass feedstocks suitable for Connecticut; Objective 2: Genetic Improvement of Poplar Plants for Bioenergy Applications; Objective 3: Improve Economic Competitiveness of Biodiesel; Objective 4: Economic impact analysis and outreach.
Project Methods
Objective 1: Assessing, mapping, and quantifying biomass feedstocks suitable for Connecticut: The overall objective of this sub-project is to create a comprehensive inventory of biomass feedstocks, including energy crops well-adapted to local conditions, and available industrial products from household, community, industrial, or agricultural streams, available to support the Connecticut bio-energy industry, and to conduct thorough evaluation of the effects of biomass feedstock production on energy supply, agriculture and rural development, and the environment. Objective 2: Genetic Improvement of Poplar Plants for Bioenergy Applications: The goal of this subproject is to evaluate growth performance and biomass production of transgenic poplar plans and determination of stem cell size and number, lignin and cellulose contents, fiber length, contents, and yields of transgenic poplar. Vegetatively propagate selected transgenic poplar lines wil be used for all proposed experiments. Two lines from each of the following groups: weak expressers, medium expressers and strong expressers of GhDET2 gene, GhGA 20-oxidase gene or both genes will be selected. Fast growing poplar can be an important bioenergy feedstock for the state of CT and the region. Objective 3: Improve Economic Competitiveness of Biodiesel: The goal of this sub-project is to expand feedstock usage in biodiesel production to include low cost waste materials and value engineer the production equipment to minimize required capitol investment. Electricity production, fine chemicals and polymers may all be produced from either the biodiesel product or the glycerol co-product. Improved reactor designs will be sought for both the triglyceride transesterification and free fatty acid esterification reactors. Heat integration of the production equipment with compatible production systems will lower operating costs. More cost effective technologies for converting glycerol to synthesis gas, direct use of glycerol in fuel cells, and interactive electric power rate optimization will be explored for electricity production. The derivatization of glycerol for use as a blending agent with protein based plastics will be explored as a means of enhancing the glycerol value. power generation (State of CT). Objective 4: Economic impact analysis and outreach: Integral to the research agenda is inclusion of analyses of economic benefits adoption of these plants, production technologies, and use of bio-energy would have on Connecticut and, possibly, the northeast. Such analyses would, for example, seek to evaluate the benefits of utilizing different feed stocks and conversion technologies, projecting new employment and output from local bio-energy feedstock production and refining, assessing the impact of new research dollars, and measuring the value of potential improvements in health and the environment. The regular provision of up-to-date assessments of the economic impacts of bio-energy will inform policy discussion, will facilitate public understanding of bio-energy, and will encourage in-state commercial development of feedstock production and commercial scale refining.

Progress 08/15/08 to 08/14/10

Outputs
OUTPUTS: Outputs: This special grant evolved from a collaborative federal appropriation proposal and contributed to the progress of meeting the renewable energy needs of CT. Ojective 1: Dr. Yang and his team developed a land-use suitability model for assessing the spatial extent and distributon of a potential biofuel feedstock (hybrid poplar) in Tolland County, CT. This model was expanded to study the feedstock potential in the State of CT. Dr. Yang's work on CT biomass was presented at the Northeastern Biomass Summit and the CT Energy Conference. Objective 2: Dr. Li's team demonstrated that "gene deletor" technology works efficiently under field conditions. Transgenic poplar plants were produced with altered hormone contents. These plants were grown under greenhouse conditions and were used in experiments to extensively characterize these transgenic plants at the molecular, physiological and morphological levels. Results showed that transgenic manipulation of plant hormone contents in poplar trees led to many changes in whole plant growth and development, and also in chemical compositions of wood cells. Some of these alterations may be of significance to bioenergy applications. Objective 3: With the work supported by this grant, Dr. Parnas obtained a $598,000 from the State of CT to establish a BQ9000 certified quality testing laboratory to provide low cost services to CT-based biodiesel producers, distributors and user. Dr. Parnas also obtained DECD support for UConn graduate students to be placed as interens at the DECD to gain administrative experience in sustainable energy management. Objective 4: Funds were used to support Connecticut Center for Economic Ananlysis' revision to its 2005 review entitled "Biodiesel: Fuel for Thought, Fuel for Connecticut's Future." Project research was presented at the 2008 UConn Biofuels Symposium, attended by over 300 people. PARTICIPANTS: Dr. Fred Carstensen, Dept. of Economics. Dr. Yi Li, Dept of Plant Science. Dr. Richard Parnas, Dept of Chemical, Material and Biomolecular Engineering. Dr. Xiusheng Yang, Dept of Natural Resources and the Environment. Each of these are full professors at the Univeristy of Connecticut and lead research teams concentrating in their areas of specialtiy as described. Dr. Ian Hart, College of Agriculture and Natural Resources, acted as the grant coordinator and administraor. TARGET AUDIENCES: Universities, Industries and Federal, State and local governments interested in the topic of sustainable energy. PROJECT MODIFICATIONS: Not relevant to this project.

Impacts
Dr. Parnas has been recognized for his work on biofuels processing by being invited to speak at universities and public forums on the topic of his latest patent and publication in "Green Engergy." Dr. Carstensen's activities as part of the CT Center of Economic Analysis (CCEA) have led to a CT legislative hearing which persuaded the Legislature and Governor to reclassify Biodiesel as a class A alternative in the state thus making it eligible for tax incentives. This project will continue with funds award by the Department of Energy.

Publications

  • M. B. Boucher, C. Weed, N.E. Leadbeater, B.A. Wilhite, J.D. Stuart, R.S. Parnas, Pilot Scale Two-Phase Continuous Flow Biodiesel Production via Novel Laminar Flow Reactor-Separator, Energy Fuels, 23(5), 2750-2756, (2009)
  • Osburn L., Yang X.3, Li Y., and ZM Cheng (2009) Micropropagtion of Japanese Honeysuckle (Lonicera japonica) and Amur Honeysuckle (L. maackii) by Shoot Tip Culture. J. Environ.Hort. 27(4):195-199
  • Ye X., Kang B., Osburn L., Li Y., Z. Cheng (2009): Identification of the flavin-dependent monoxygenase-enase-encoding YUCCA gene family in Populustrichocarpa and their expression in vegetative tissues and in response to hormone and environmental stresses. Plant Cell, Tissue and Organ Culture (PCTOC: J. of Plant Biotechnology) 97: 271-283
  • Kausch A, Hague J, Oliver M, Li Y, Daniell H, Mascia P, Watrud L, and C. Neal Stewart, Jr. (2010): Transgenic biofuel feedstocks and strategies for biocontainment. Biofuels. 1: 163-176
  • S.U. Unker, M.B. Boucher, K.R. Hawley, J.D. Stuart and R.S. Parnas, Investigation into the relationship between the gravity vector and the flow vector to improve performance in two-phase continuous flow biodiesel reactor, Bioresource Technol., 101, 7389-96, (2010)


Progress 08/15/08 to 08/14/09

Outputs
OUTPUTS: This special grant evolved from a collaborative federal appropriation proposal which was desiged to:(1)create a comprehensive inventory of potential biomass feedstocks in CT, (2)use "gene deletor" technology to improve feedstocks for energy generation, (3)develop industry-scale processing technologies and co-generation for CT biofuels (eg: biodiesel), and (4)carry out an economic impact analysis of adopting these technologies in CT and the northeast. The project was only been funded ($200,000)for one year with no chance of USDA continuation. Although the collaborators have published extensively on these topics in the past and have, in one case, issued patents, there has been limited research progress or dissemination of results with these limited funds. It is pleasing to note that the project will be supported with DOE funds ($1.5M) in the future. Some of Dr. Yang's work on CT biomass has been presented at the Northeastern Biomass Summit and the CT Energy Conference. Dr. Parnas has been recognized for his work on biofuels processing by being invited to speak during the last year at over a dozen universities and public forums on the topic of his latest patent and publication in "Green Energy." Dr. Carstensen's activities as part of the CT Center for Economic Analysis (CCEA) have led to a CT legislative hearing which persuaded the Legislature and Governor to reclassify Biodiesel as a class A alternative in the state thus making it eligible for tax incentives. US Patent 7,544,830, R.S. Parnas, C. Weed, N. Leadbeater, M. Boucher, Methods and systems for alkyl-ester production, June 9, 2009. PARTICIPANTS: Dr. Fred Carstensen, Dept. of Economics. Dr. Ian Hart, College of Agriculture and Natural Resources. Dr. Yi Li, Dept of Plant Science. Dr. Richard Parnas, Dept of Chemical, Material and Biomolecular Engineering. Dr. Xiusheng Yang, Dept. of Natural Resources and the Environment. Each of these are full professors at the University of Connecticut. Dr Hart acted as the grant coordinator and administrator. Each of the remaining faculty lead research teams concentrating in the areas of speciality described in the report. TARGET AUDIENCES: Universities, Industries and Federal, State and local government interested in the topic of sustainable energy. PROJECT MODIFICATIONS: Not relevant to this project.

Impacts
Dr. Yang and his team used some of these funds to develop a land-use suitability model for assessing the spatial extent and distribution of a potential biofuel feedstock (hybrid poplar) in Tolland County, CT. Preliminary results indicate that about 50% of the total land in this rural county is available for use and that less than 10% is suitable for hybrid poplar silviculture. It appears that woody energy crops may not be an adequate replacement as feedstock for ethanol production but rather a supplemental resource. The model is currently being evaluated and expanded to study the feedstock potential of the whole of the State of CT. Dr. Li's team has demonstrated that the "gene deletor" technology works efficiently under field conditions and are in the process of demonstrating the complete deletion of transgenes from the reproductive organs. His team has also generated transgenic poplar plants that grow much faster than the native species under greenhouse conditions. The additional growth was due to an increase in stem lenth due to an increase in both cell number and size. Work partially supported by this grant helped Dr. Parnas obtain a $598,000 from the State of CT to establish a BQ9000 certified quality testing laboratory to provide low cost services to CT-based biodiesel producers, distributors and users. The special grant also helped Dr. Parnas to obtain separate CT DECD support to place UConn graduate students as interns at the DECD to gain administrative experience in sustainable energy management. Finally this award has enabled the CCEA to start to revise and update its 2005 review entitled "Biodiesel: Fuel for Thought, Fuel for Connecticut's Future." Currently in draft, the study significantly expands the analysis in several areas.

Publications

  • Boucher, M.B., Unker, S.A., Hawley, B.A., Wilhite, J.D., Stuart, J. and Parnas, R.S. 2008. Variables affecting homogeneous acid catalyst recoverability and reuse after esterification of concentrated omega-9 polyunsaturated fatty acids in vegetable oil triglycerides. Green Chemistry 10:1331-1333