Source: PENNSYLVANIA STATE UNIVERSITY submitted to NRP
CHARACTERIZATION OF FLAVOR MOLECULES IN FOODS
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0211980
Grant No.
(N/A)
Cumulative Award Amt.
(N/A)
Proposal No.
(N/A)
Multistate No.
(N/A)
Project Start Date
Oct 1, 2007
Project End Date
Aug 31, 2009
Grant Year
(N/A)
Program Code
[(N/A)]- (N/A)
Recipient Organization
PENNSYLVANIA STATE UNIVERSITY
208 MUELLER LABORATORY
UNIVERSITY PARK,PA 16802
Performing Department
FOOD SCIENCE
Non Technical Summary
Flavor is considered to be the greatest single factor in determining our choice of food; key criteria of food quality. This project is aimed at understanding the flavor properties of foods by identifying aroma- and taste-active compounds, defining how food composition impacts flavor generation as well as food-flavor interactions which influence the release properties and subsequent perception of these flavor compounds. The overall impact of this work will be to facilitate food processors and manufacturers to provide high quality flavorful foods in the state and beyond.
Animal Health Component
40%
Research Effort Categories
Basic
50%
Applied
40%
Developmental
10%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
5015010200025%
5025010200075%
Goals / Objectives
1. Analytically define the character impact flavor compounds in food products. 2. Investigate the influence of food composition on flavor generation. 3. Define physico-chemical properties of food products that affect the release kinetics of aroma compounds. The influence of molecular interactions, inclusions, and bulk properties (e.g. viscosity) on the flavor release properties will be investigated.
Project Methods
1. Identification of key flavor compounds will be performed by a combination of analytical and sensory techniques. The isolate will be collected via headspace, distillation, extraction methods and subjected to the gas chromatography-olfactometry technique (i.e. Aroma Extract Dilution Analysis) for the characterization of individual odorants and LC-taste techniques (i.e. Taste Dilution Analysis) will be used for the identification of taste-active compounds. The key compounds will be identified by their linear retention indices on two columns of different polarity, mass spectra, odor characteristics, NMR spectra, etc. 2. The mechanisms of flavor generation will be investigated in food and simple model systems by various analytical techniques, such as gas chromatography-mass spectrometry, liquid chromatography-mass spectrometry, isotope labeling techniques, derivatization techniques, etc. 3. The flavor release profile will be analytically monitored by breath analysis techniques (i.e. APCI-MS). Both model and food systems will be used to investigate flavor-ingredient interactions on the flavor release profiles. This information will be used to characterize analytically how various food macromolecules and micromolecules influence the release properties of flavor compounds. These instrumental findings will be related to flavor perception via sensory methodologies (time-intensity, descriptive analysis).

Progress 10/01/07 to 08/31/09

Outputs
OUTPUTS: Research was conducted in the context of graduate education. PARTICIPANTS: Alicia Holt TARGET AUDIENCES: Food Science Industry/Academia PROJECT MODIFICATIONS: Nothing significant to report during this reporting period.

Impacts
The influence of aroma compound structure and acidulants on the aroma release profile and the flavor perception of hard candy were investigated. In aqueous model systems, the addition of aroma compounds separately versus as a mixture resulted in an aroma release profile that was more rapid and higher in concentration; particularly for aroma compounds with a similar molecular structure. However, the addition of an acidulant to the models did suppress the aroma release for the separate flavor addition technique; although the release profile was still higher in concentration in comparison to the mixture flavor addition technique. Similarly, in hard candy, the aroma release monitored by breath analysis was higher in concentration and was perceived to be more intense by a sensory panel for the separate versus mixture flavor dosed sample formulated with malic acid. In summary, interactions between the flavor compounds themselves were reported to influence the flavor performance of hard candy.

Publications

  • No publications reported this period


Progress 10/01/07 to 09/30/08

Outputs
OUTPUTS: In chewing gum, the release profile of cinnamaldehyde and sorbitol during the initial phase of chewing gum mastication were reported to be correlated, which was in contradiction to the log cP model. Transient hemi-acetal reactions as a mode of flavor delivery are suggested and supported by tandem mass spectrometry. The increased polarity of these cinnamaldehyde-sorbitol reaction products resulted in a more rapid release rate for cinnamaldehyde than would be predicted by the log cP method. Different flavor solvents uniquely influenced flavor delivery in chewing gum. A relationship between gum base plasticity and retention of sugar alcohol during mastication was proposed to explain the different flavor properties based on solvent interactions. In dispersions, solid lipid particles had a weaker interaction with flavor compounds the liquid oil particles. In starch models, flavor interactions were related to water solubility. PARTICIPANTS: Rajesh Potineni (graduate student) Supratim Ghosh (graduate student) Onanong Tapanapunnitiku (graduate student) John Coupland (co-PI) Don Thompson (co-PI) TARGET AUDIENCES: Food/Pharmaceutical Industry, academia PROJECT MODIFICATIONS: Not relevant to this project.

Impacts
An improved understanding of flavor delivery mechanisms in food/confections were defined. This information was used to leverage new research funds for further graduate education.

Publications

  • Potineni, R.V. and D.G. Peterson. 2008. Mechanisms of flavor release in chewing gum: Cinnamaldehyde. J. Agric. Food Chem. 56, 3260-3267.
  • Potineni, R.V. and D.G. Peterson. 2008. Influence of flavor solvent on flavor release and perception in sugar-free chewing gum. 2008. J. Agric. Food Chem. 56, 3254-3259.
  • Tapanapunnitikul, O., S. Chaiseri, D. Peterson, and D. Thompson. 2008. Water solubility of flavor compounds influences formation of flavor inclusion complexes from dispersed high-amylose maize starch. J. Agric. Food Chem. 56, 220-226.
  • Ghosh, S., D.G. Peterson, and J.N. Coupland. 2008. Temporal Aroma Release Profile of Solid and Liquid Droplet Emulsions. Food Biophysics. 3:335-343.


Progress 10/01/07 to 12/31/07

Outputs
OUTPUTS: Research and data analysis was conducted in the form of graduate education. PARTICIPANTS: Devin G Peterson, Principal Investigator, In Hee Cho, Post-Doc TARGET AUDIENCES: Food Science Industry/Academia

Impacts
Dietary phenolic compounds have reported in preliminary experiments in influence flavor development in processed foods.

Publications

  • No publications reported this period