Source: TERRENEW, LLC submitted to NRP
THE USE OF AGRICULTURAL WASTE PRODUCTS FOR ENVIRONMENTAL CLEANUP AND REMEDIATION
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0210016
Grant No.
2007-33610-17994
Cumulative Award Amt.
$79,716.00
Proposal No.
2007-00189
Multistate No.
(N/A)
Project Start Date
Jun 1, 2007
Project End Date
Feb 1, 2008
Grant Year
2007
Program Code
[8.11]- (N/A)
Recipient Organization
TERRENEW, LLC
500 TECHNOLOGY DRIVE
GENEVA,NY 14856
Performing Department
(N/A)
Non Technical Summary
Manures contribute to pollution of the environment and create disposal problems for animal producers. At the same time, farms and foresters in NYS need new outlet for waste products. In addition, oil spill recovery materials are either inconvenient, environmentally unfriendly and nonrenewable, or both. Our products address all of these problems. The purpose of this project is to produce products for oil spill recovery that are made wholly or partially from agricultural waste products. This will create new markets for NYS growers and additional employment in this State.
Animal Health Component
40%
Research Effort Categories
Basic
(N/A)
Applied
40%
Developmental
60%
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
1330699100010%
1333499100040%
4030699100010%
4033499100040%
Goals / Objectives
Terrenew has discovered that manures, and barks as well, make highly efficient oil absorption products. The oil absorption marketplace is dominated by loose granular clay materials, e.g., the kitty litter type products, that are sold in large volumes. The company will begin to sell products for this purpose, beginning in the autumn, 2006. However, for more sophisticated markets, such as oil removal from water, melt blown polypropylene is the material of choice. The objective of the proposed research is To develop cost-effective pads and sheets that include manure as an absorbent for absorption of liquid oil and aqueous wastes and spills. Bark is an alternative material. The pads and sheets are expected to contain about 50% manure as the absorbent in a nonwoven fabric that may be composed of natural or synthetic fibers. The first prototypes have already been produced and are highly effective; but for different uses, a large array of pads and sheets with different properties are necessary. These will be developed in this project. This research is expected to provide a major market for agricultural wastes and to provide at least a partial alternative to the use of expensive nonrenewable polypropylene sheets for oil and other spill remediation.
Project Methods
The systems we are pioneering will use substantial amounts of processed and dried manures for oil removal and remediation. We expect to sell loose bags of product, in products similar to, but much more effective than, clay based absorbents of the kitty litter type that are typically used for many applications. These loose products are essentially ready for commercial production; marketing issues and issues of large-scale production are the primary challenges now. In addition, we are proposing to, and have already created prototypes for pads and similar materials for oil removal from oils and waters. The pads are prepared primarily by nonwoven technologies and contain at least 50% manures. While manures are the favored materials for our uses, it also is possible to use barks, especially after aging, for similar applications. These are potentially very large uses of these materials. Based on research already completed, we will further define pads and products to ensure that our products will be cost competitive and also as effective as existing products. We expect to produce prototype commercial pads initially using facilities at Southeast Nonwovens, Clover, SC, and will use to seed the market. As time progresses, we will make pads for different applications and purposes and hope to reach full-scale production in the near future.

Progress 06/01/07 to 02/01/08

Outputs
OUTPUTS: The proposed project had a single technical goal as follows: to develop cost-effective pads and sheets that include manure as an absorbent for absorption of liquid oil and aqueous wastes and spills. Bark is an alternative material. This project has been very successful. Prototype pads were produced and a pad that contains 70% manure and 30% of a synthetic binder was identified that is highly effective in oil uptake. This pad can be made in different thicknesses and thereby its oil holding capacity can be increased or decreased. It can also be made water repellent. Sorbent materials used for removal of oil on water must be water repellent, so that they (a) do not take up water in preference to oil, or (b) sink and thereby become unrecoverable. Thus, multiple pads with the different properties needed to penetrate the marketplace were developed. In addition to the oil absorption market, potentially very large uses for the exact same manure-based pads are in horticultural markets. Instant turf, living walls and similar applications can be readily developed by growing seedlings on our pads and then transporting them to the site where they will be used. A company with a large and growing market in this area likes our pads very much. They have previously used another material, but our manure pads have advantages over these. At this time, the pads have been used to grow turf and have been successfully applied to a highly visible public project (please note: the project needs to remain confidential until there is a press release) as living roof materials. In addition, we have produced pre-seeded pads that have attracted interest from two other companies, including a national lawn and landscape company. The results have been disseminated in several ways: first, some of the data has been presented in the form of a patent, and, second, the pads are being promoted and are being test marketed. The test marketing is expected to provide a large and profitable market for Terrenew. PARTICIPANTS: Individuals Tom Bourne, CEO, Terrenew and PI Gary Harman, Chief Scientific Officer and Cornell Professor Terry Spittler, Analytic Affairs and Retired Cornell faculty member Bob Patrick, Cornell Research Technican II Organizations Southeast Nonwovens, eqipment rental for pad production Cornell University SBIR subcontract TARGET AUDIENCES: The principal target for the efforts are customers and organizations that would use our products for environmental cleanup. These include garages, auto parts suppliers, environmental consultants and others. In addition, farmers are a primary target audience since they will provide the raw materials that we use for pad production and since we can increase their economic well-being. PROJECT MODIFICATIONS: The only major change was the discovery that, in addition to oil spill cleanup, the same pads have large potential horticultural uses in plant propagation, instant lawns, erosion control and other applications. Thus, we have two major uses for the pads when we expected only to use them for oil cleanup.

Impacts
The development of pads in this phase I project has provided a number of highly advantageous outcomes. The pads as initially produced were provided to potential customers for their evaluation. The oil absorbent pads were as, or more, oil absorbent than conventional pads. These are being sold now in small quantities for garages and similar operations, but there were disadvantages to them. The primary disadvantage was that the pads flaked the larger manure particles and this was undesirable for clean garage applications. We have arrived at several possible solutions to this problem and it is well on the way to solution. Another necessary development was production of pads that do not absorb water. If the pads are used for oil spill cleanup on water, water absorption must be avoided. We have arrived at inexpensive waterproofing systems for the pads. The pads have a major advantage over those in use now. Most of the pads are produced from petroleum-based polypropylene, and our pads are primarily (70%) composed of manure, which is an agricultural waste product. Thus, our pads are much more environmentally friendly. Moreover, the developments of the pads have the potential to provide additional revenue to dairy farms, which is an advantage. Finally, the full development of the pads is expected to provide a large market; the total market for such pads is more than 1 billion dollars, and so there is a large economic benefit, including job creation, from these technologies. Finally, the energy and financial costs of transportation of pads and almost any other product is large. Since manure is produced everywhere, we expect to be able to minimize shipping costs by regional manufacturing operations.

Publications

  • Harman, G. E., T. D. Spittler, S. F. Neilsen, and B. P. Thomas. 2007. Removal of oils from solid surfaces and water with a substance having a high humate level, PCT WO2007035672.