Source: ELTRON RESEARCH, INC. submitted to NRP
AUTOMATED FOULING MITIGATION SYSTEM FOR DAIRY FILTRATION MEMBRANES
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0197114
Grant No.
2003-33610-14035
Cumulative Award Amt.
(N/A)
Proposal No.
2003-04074
Multistate No.
(N/A)
Project Start Date
Sep 15, 2003
Project End Date
Sep 14, 2005
Grant Year
2003
Program Code
[8.5]- (N/A)
Recipient Organization
ELTRON RESEARCH, INC.
4600 NAUTILUS COURT SOUTH
BOULDER,CO 80301
Performing Department
(N/A)
Non Technical Summary
Filtration membranes in the dairy industry for milk and cheese whey processing are to be cleaned and disinfected every 24 hours. Typical filtration plants for large-scale dairy processing have hold-up volumes of 1000-2000 gallons requiring large volumes of cleaning solutions and large quantities of chemical cleansers. Reducing cleanser cost and the environmental impact of spent cleanser discharge, especially chlorine and chlorinated byproducts, will benefit the economics of dairy processing and reduce chemical hazards to the environment. Additionally, filtration membranes are easily damaged by chlorine whereas they are tolerant to much greater levels of hydrogen peroxide. Hydrogen peroxide also auto-decomposes to water and oxygen making it environmentally benign. However, the cost of hydrogen peroxide traditionally exceeds that of chlorine or hypochlorite. The electrolytic technology in this program will produce hydrogen peroxide solutions consuming water, electricity, and oxygen from air for a fraction of the cost of bulk sources making its use an economically viable alternative to chlorine. The automated system based on this technology will generate cleanser solutions effective for cleaning and disinfecting filter membranes used in dairy processing at a fraction of the cost of bulk cleanser concentrates. Cleanser solutions will be generated on-site at the proper concentrations minimizing the use of bulk chemical concentrates. This system will be interfaced as an add-on to the current clean in place cleanser distribution systems used to maintain filter plants.
Animal Health Component
100%
Research Effort Categories
Basic
(N/A)
Applied
100%
Developmental
(N/A)
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
5013430202025%
5013450204075%
Goals / Objectives
The overall goal of the Phase II program is producing an automated system for electrolytically generating cleansing and disinfecting chemicals necessary for maintaining dairy processing filtration systems. Achieving this goal will occur by addressing the following objectives: optimize electrolytic cell performance, increase mechanical stability of the system, reduce materials and production costs of the system, optimize cleanser compositions for a variety of membrane foulants relevant to dairy processing, and scale up the electrolytic cell capacity. Meeting these objectives will result in the design, construction and demonstration of a pilot-scale membrane cleaning system. Successfully addressing each of these objectives during the Phase II program will result in a verified prototype system for pilot-scale demonstration, testing, marketing, and development with a third party investor and manufacturer
Project Methods
The general approach taken in this program is to develop a unique three-chamber electrolytic cell that produces, acid, caustic, and hydrogen peroxide cleanser solutions for cleaning ultrafiltration and reverse osmosis membranes used in dairy processing and other sanitary membrane processing applications. This unique electrolytic system produces cleansers for a fraction of the cost of bulk chemical concentrates, reduces worker exposure to concentrated chemicals, eliminates the storage of such chemicals, and employs environmentally-gentle hydrogen peroxide rather than chlorine as a disinfectant. The electrolytic cell system for prototype demonstration will be designed to generate pilot-scale quantities of these cleanser solutions. The effectiveness of these cleanser solutions will be verified by repeatedly fouling filtration membranes with whey proteins, milk fat, mineral deposits, lactose sugars, etc. followed by cleaning with electrolytically generated cleansers while monitoring changes in filter membrane performance and analyzing residual bacterial levels.

Progress 09/15/03 to 09/14/05

Outputs
A unique electrolytic technology has been successfully developed and tested for producing cleanser solutions for cleaning and disinfecting filtration membranes and equipment used in dairy processing. The system produces acid, caustic and hydrogen peroxide solutions on-site and on-demand at the necessary concentrations and be easily appended to a clean in place system. Consumables are only water, electricity, and oxygen in air, in the presence of small amounts of supporting electrolytes. The primary benefit this technology provides is a substantial cost savings in producing the cleansing chemicals. This technology also eliminates the need to handle and store large quantities of strong chemical concentrates (acids, caustics, bleach or hydrogen peroxide) as well as eliminate the use and discharge of chlorine or chlorinated byproducts. The cleansers produced by this technology are effective without surfactants and are safe to use in filter plants and clean in place systems. Cleansers produced by this technology were superior in mitigating membrane fouling in comparative tests with commercial cleansers. These cleanser solutions were also successful in eliminating bacterial species purposely inoculated into a small filtration apparatus including Escherichia coli, Staphylococcus epidermis, Bacillus cereus, Bacillus subtilis and indigenous background organisms. Corrosive strength of cleanser solutions was determined. The electrolytic cell-produced cleansers are similar in corrosive strength to standard commercial cleansers, which is minimal in stainless steel dairy equipment and filter plants. A unique electrolytic cell is the core technology of the cleaning system. Performance of the electrolytic cell was studied under carefully controlled conditions to parameterize the optimization of electrolytic cell performance, especially production efficiency and rate. Electrolytic cell fouling and cleaning was explored to determine methods of field maintenance. Water quality requirements for hydrogen peroxide production were also determined. The electrolytic cell was redesigned for scale up and produced on a pilot production scale. The technology output performance was defined by testing it in a large prototype system and was re-packaged into a demonstration unit for marketing. The results of work conducted were completely successful in demonstrating the viability of the technology for the targeted application. A number of potential customers for several other applications in water treatment have also shown significant interest, and field demonstrations are being negotiated. A trademark for the hydrogen peroxide generation technology was created, PeroxEgenTM, and application for several patents will be made.

Impacts
The electrolytic cleanser production technology provides a number of benefits. The financial benefit is an estimated 75-85% cost savings in purchased cleanser products. The economic use of hydrogen peroxide-based cleansers is enabled by this technology. The safety benefits are cleanser solutions can be produced on site and on demand at the necessary concentrations thereby eliminating the need to transport, handle and store significant quantities of harmful chemicals and strong oxidizers in concentrated form. The environmental benefits are the elimination of chlorine and chlorinated byproduct discharge and the reduction of surfactant use and discharge.

Publications

  • No publications reported this period


Progress 09/15/03 to 09/15/04

Outputs
A unique electrolytic technology has been successfully developed and tested for producing cleanser solutions for cleaning and disinfecting filtration membranes and equipment used in dairy processing. The system produces acid, caustic and hydrogen peroxide solutions on-site and on-demand at the necessary concentrations and be easily appended to a clean in place system. Consumables are only water, electricity, and oxygen in air, in the presence of small amounts of supporting electrolytes. The primary benefit this technology provides is a substantial cost savings in producing the cleansing chemicals. This technology also eliminates the need to handle and store large quantities of strong chemical concentrates (acids, caustics, bleach or hydrogen peroxide) as well as eliminate the use and discharge of chlorine or chlorinated byproducts. The cleansers produced by this technology are effective without surfactants and are safe to use in filter plants and clean in place systems. Cleansers produced by this technology were superior in mitigating membrane fouling in comparative tests with commercial cleansers. These cleanser solutions were also successful in eliminating bacterial species purposely inoculated into a small filtration apparatus including Escherichia coli, Staphylococcus epidermis, Bacillus cereus, Bacillus subtilis and indigenous background organisms. Corrosive strength of cleanser solutions was determined. The electrolytic cell-produced cleansers are similar in corrosive strength to standard commercial cleansers, which is minimal in stainless steel dairy equipment and filter plants. A unique electrolytic cell is the core technology of the cleaning system. Performance of the electrolytic cell was studied under carefully controlled conditions to parameterize the optimization of electrolytic cell performance, especially production efficiency and rate. Electrolytic cell fouling and cleaning was explored to determine methods of field maintenance. Water quality requirements for hydrogen peroxide production were also determined. The electrolytic cell was redesigned for scale up and produced on a pilot production scale. The technology output performance was defined by testing it in a large prototype system and is now in the process of being re-packaged into a demonstration unit for marketing. The results of work conducted thus far are completely successful in demonstrating the viability of the technology for the targeted application. The remainder of the program will be primarily spent on improving system packaging and performance, automating system operation, demonstration, and marketing.

Impacts
The electrolytic cleanser production technology provides a number of benefits. The financial benefit is an estimated 75-85% cost savings in purchased cleanser products. The economic use of hydrogen peroxide-based cleansers is enabled by this technology. The safety benefits are cleanser solutions can be produced on site and on demand at the necessary concentrations thereby eliminating the need to transport, handle and store significant quantities of harmful chemicals and strong oxidizers in concentrated form. The environmental benefits are the elimination of chlorine and chlorinated byproduct discharge and the reduction of surfactant use and discharge.

Publications

  • No publications reported this period