Source: VERIS TECHNOLOGIES submitted to NRP
A SOIL SAMPLING SYSTEM FOR ON-THE-GO ANALYSIS AND MAPPING OF PH AND OTHER PROPERTIES
Sponsoring Institution
National Institute of Food and Agriculture
Project Status
COMPLETE
Funding Source
Reporting Frequency
Annual
Accession No.
0196964
Grant No.
2003-33610-14016
Cumulative Award Amt.
(N/A)
Proposal No.
2003-04068
Multistate No.
(N/A)
Project Start Date
Sep 1, 2003
Project End Date
Aug 31, 2006
Grant Year
2003
Program Code
[8.4]- (N/A)
Recipient Organization
VERIS TECHNOLOGIES
601 N. BROADWAY
SALINA,KS 67401
Performing Department
(N/A)
Non Technical Summary
As crop growers begin to use GPS technology to manage the variability in their fields, they are seeking ways to assess the variability of physical and chemical properties more accurately and cost-effectively. In the most common approach, soil samples are acquired on a 2.5 acre grid pattern. Soil properties often have greater spatial variability than is identified with this approach, however the costs of sampling and lab analysis preclude denser sampling. A promising approach to this problem is to use ion-selective electrodes that measure soil properties on-the-go much more intensively than 2.5 acres/sample. A soil-sampling mechanism was prototyped by Purdue University for sensing soil pH. This device was re-designed and extensively field-tested with pH electrodes during a Phase I project. On-the-go pH sensing has proven feasible and is viable for commercial development. Validation of pH sensor data during earlier research confirmed the economic advantages of dense, on-the-go mapping versus current sampling methods. In the new project, several user-oriented features will be integrated for commercial use, and advancements will be made in using other ion-selective electrodes, and in prescribing applications from sensor data.
Animal Health Component
100%
Research Effort Categories
Basic
(N/A)
Applied
100%
Developmental
(N/A)
Classification

Knowledge Area (KA)Subject of Investigation (SOI)Field of Science (FOS)Percent
1010110200025%
1010110206125%
1015310200025%
1015310206125%
Goals / Objectives
The first objective for this project will be to construct a new prototype soil pH sampling system with multiple sensor modules and EC electrodes. Here are some specific objectives for this system: 1) hydraulic power will come from a small gasoline engine powering a hydraulic pump, 2) wheel and electrode spacing will allow mapping growing 30" row crops, 3) operating cost of electrodes will be improved through breakage resistant design, 4) electrode holder will be redesigned, making it easier to calibrate, remove, store, and change electrodes, 5) controller module controlling of automated cycling functions of multiple electrodes will be developed, 6) Veris instrument and/or field computer will measure soil EC simultaneously with logging ISE data, 7) operating software will be written that reviews sensor data during data collection and interacts with controller module, 8) software will be written that will recognize when the electrodes have stabilized, according to predetermined criteria, 9) a warning function will be added that notifies the operator whenever sensor response indicates a possible electrode or mechanism failure, 10) pH calibration procedure will be added, and 11) validation of the new automated system. The second set of objectives relates to additional electrode capability. The sampling system will be outfitted with K, N, Na electrodes, and a comprehensive set of field tests will be conducted. The sensor data will be validated with lab analyzed soil samples, the durability and reliability of electrodes in lab and in the field will be evaluated, and operational issues such as calibration, electrode cleaning, and controls will be optimized. The third set of objectives is for deriving prescriptive information from on-the-go mapping using optical and EC data along with ion-selective-electrode mapping. This entails using ion-selective electrodes to map the spatial variability in pH, K, and N, and deriving a lime, potash, and nitrogen application information using optical and EC data along with advanced geo-statistical techniques. The accuracy performance criteria for all testing will involve comparing the results of this automated system to the results of conventional and grid sampling. The durability criteria are similar-comparing the cost of using the automated system with grid sampling.
Project Methods
Two identical new prototypes will be designed and constructed. They will include two alternately cycling ion-selective-electrode modules, and six EC coulter-electrodes spaced to avoid damage to row crops. These will be pull-type implements for use with either tractor or 4WD pickup truck. These will feature continued improvements in electrode durability, cleaning and holding. The existing controller module will be redesigned to control automated cycling functions of alternately cycling ion-selective-electrode modules. Software will be created for the Veris instrument that will monitor data from the ion-selective-electrode, and warn operator of any data collection problems, based on criteria such as electrode stabilization, or change in reading from previous sample. A pH calibration procedure will be added to the system, where the electrodes are brought in contact with a buffer 4 and buffer 7 (and/or 10) solution, the operator initiates a calibration mode, and the software adjusts data collected since last calibration. Additional calibration methods will also be considered, including monitoring the pH during the washing cycle and calibrating based on electrode performance during washing. For validation of the ion-selective data, several fields with contrasting soils and conditions will be mapped, sampled, lab-analyzed, and the results compared to the sensed data. Validation of automated sensing will be done in regions of the US where the property of interest-pH, potassium, nitrogen, and sodium are considered important by local consultants and growers. Sampling fields for validation will be done using both grids and targeted samples. First, the field will be grid sampled on a basis that most closely approximates typical commercial sampling: 1 acre and/or 2.5 acre grids, with 8-10 cores in a 15-20' radius around the center point of grid, with the center point geo-referenced with DGPS. On each field, 5-10 targeted calibration samples per field will be chosen within areas that showed spatially structured pH. It has been previously shown that water used in the field affects electrode output. Distilled and deionized water are used in a laboratory setting to reduce this effect. However, potential customers for the automated soil mapping system will wish to use alternative water sources. Therefore, a study will be conducted to quantify the effects of various water sources and to provide a recommendation regarding the usage of non-purified water. Laboratory and field data obtained through this task will be used to develop recommendations on appropriate utilization of the commercialized automated pH system. Geostatisical, agronomic, and economic evaluations will be combined to demonstrate the effects of various mapping densities on errors, and to compare the value of information obtained with the mapping cost.

Progress 09/01/03 to 08/31/06

Outputs
Technological advancements are needed to cost-effectively improve the precision of soil nutrient information. On-the-go soil sampling has the potential of improving the density of soil chemical property information at an affordable cost. In a Phase I project, Veris Technologies demonstrated the feasibility of pH mapping, with a sampling device that collected soil cores, measured pH directly on the cores utilizing ion-selective electrodes (ISE's), and discharged the cores on-the-go. The purpose of the Phase II project was threefold: 1) to develop the Phase I sensing device into a complete pH sensing system, 2) to further develop the system to include other ion-selective electrodes, and 3) to develop the capability of deriving prescriptive information, such as lime requirement, in conjunction with other sensor data. In order to develop a pH sensing system capable of operating in a wide variety of soil and field conditions, the mechanical, hydraulic, and electronic components of the system were configured, designed, tested, and refined. For commercial viability, the system needed to be relatively simple and easy to operate, and capable of collecting high-quality pH data with a volume of 200 acres/day. Phase II research has resulted in such a pH sensing system, termed the Veris Mobile Sensor Platform (MSP), with initial commercialization underway. Research conducted on this system has shown it to be proficient in collecting field-sensed pH measurements that are well-correlated to lab-analyzed validation samples. Prescriptive information using sensed pH, along with a small number of calibration samples and other sensor information such as soil electrical conductivity (EC), has been shown to be effective for generating precise lime recommendations. A limitation of the current MSP is reduced pH electrode life in sandy soils, resulting in high per-acre operating costs when used in those soils. Direct soil measurement using ISE's for measuring potassium (K) and nitrate (N) were deemed not commercially viable, due to the fragility and operating expense of those electrodes. To address this challenge, a significant innovation for the MSP was designed and tested: a module which creates a soil-water solution measurement. Not only does this innovation allow the use of expensive, fragile electrodes such as those for N and K, it offers much longer wear life and reduced operating costs for pH as well. Commercialization of the MSP with direct-soil pH measurement has resulted in systems operating in ten states and three foreign countries. Response to the system has generally been positive, and it is expected that the introduction of the soil-solution module will lead to increased consumer acceptance and higher sales volumes. A patent on the standard MSP is pending, and it is anticipated that patent coverage on the soil-solution module will be sought as well.

Impacts
In the United States, there are approximately 135,000,000 acres of low pH soils. Worldwide, 45% of all arable land suffers from low pH. All current methods of soil sampling estimate the soil pH at un-sampled locations, either by averaging the composited values or by interpolating the values of individual samples. The density of the data collected by the Veris Mobile Sensor Platform reduces the error associated with these sampling methods. In field tests conducted under Phase 2, the spatial variability of soil pH on many fields has been demonstrated, and the improvements in pH accuracy made by the Veris Mobile Sensor Platform are significant. As the first commercial system capable of mapping a soil chemical property on-the-go, the Veris pH Manager has generated widespread interest in improved mapping. Units have been sold in 10 states and three foreign countries. The detailed lime prescriptions offer a significant improvement in lime accuracy, which should ultimately improve yields, nutrient utilization, and growers' profits. Also, an on-the-go soil-solution creating system has been developed and tested, which represents a major advancement in on-the-go nutrient mapping capability. This device has been shown to provide accurate potassium mapping, however nitrate tests weren't as promising. Once successfully commercialized, this module has the potential to significantly improve usage of potash, and possibly nitrogen.

Publications

  • Lund, E.D., and V.I. Adamchuk, 2006. On-the-go Mapping of Soil pH and Other Soil Properties Using Ion-Selective Electrodes in a Soil-Water Solution. Proceedings of 8th International conference on Precision Agriculture, Minneapolis MN
  • Lund, E.D., V.I. Adamchuk, K.L. Collings, P.E. Drummond and C.D. Christy. 2005. Development of soil pH and lime requirement maps using on-the-go soil sensors. Proceedings of 5th European Conference on Precision Agriculture Malmo Sweden
  • Adamchuk, V.I., E.D. Lund, B. Sethuramasamyraja, M.T. Morgan, A. Dobermann, D.B. Marx. 2005. Direct measurement of soil chemical properties on-the-go using ion selective electrodes. Computers and Electronics in Agriculture 48(3):272-294.
  • Lund, E.D., V.I. Adamchuk, K. L. Collings, P. E. Drummond, and C. D. Christy. 2004. Managing pH Variability With On-The-Go pH Mapping. Proceedings of 7th International conference on Precision Agriculture, Minneapolis MN


Progress 01/01/05 to 12/31/05

Outputs
This project has resulted in a commercially available pH mapping system, the Veris Mobile Sensor Platform featuring the pH Manager. These machines have been purchased by ag input suppliers, crop consultants, and researchers in 12 states and 3 foreign countries. During the early part of the Phase II project, efforts focused on developing the control and measurement functions required to measure pH on the go. Fine-tuning these functions continues today. At all phases of the project, sensor-derived pH and lime maps were validated with lab-analyzed soil samples. The validation process has evolved into a field-calibration and lime requirement modeling software routine. This method involves collecting 5-10 lab-analyzed soil samples, and performing a multiple regression routine that uses the lime recommendations from the lab, soil electrical conductivity (as a surrogate measure of soil buffering) and the on-the-go pH sensor data to generate a lime rec for each pH sensor data point. After meeting these objectives relating to pH measurements, recent efforts have centered around developing a system for measuring soluble potassium and nitrate nitrogen using ion-selective electrodes. Due to the abrasive nature of soils and the fragility of the PVC membranes on these electrodes, direct-soil measurement is not feasible. A system which creates a soil-water mixture has been developed and is being field-tested. The balance of the Phase II project will focus on additional development and field-validation of this system.

Impacts
As the first commercial system capable of mapping a soil chemical property on-the-go, the Veris pH Manager has generated widespread interest in improved mapping. The detailed lime prescriptions offer a significant improvement in lime accuracy, which should ultimately improve yields, nutrient utilization, and grower profits. The nitrate and potassium mapping option, if successfully commercialized, has the potential to significantly improve usage of these fertilizers.

Publications

  • Lund, E.D., V.I. Adamchuk, K.L. Collings, P.E. Drummond and C.D. Christy. 2005. Development of soil pH and lime requirement maps using on-the-go soil sensors. Proceedings of 5th European Conference on Precision Agriculture Malmo Sweden
  • Adamchuk, V.I., E.D. Lund, B. Sethuramasamyraja, M.T. Morgan, A. Dobermann, D.B. Marx. 2005. Direct measurement of soil chemical properties on-the-go using ion selective electrodes. Computers and Electronics in Agriculture 48(3):272-294.
  • Lund, E.D., V.I. Adamchuk, K. L. Collings, P. E. Drummond, and C. D. Christy. 2004. Managing pH Variability With On-The-Go pH Mapping. Proceedings of 7th International conference on Precision Agriculture, Minneapolis MN


Progress 10/01/03 to 09/30/04

Outputs
This project was divided into three parts: 1) Creation of a pH sensing system, 2) Further develop the system to include other ion-selective electrodes (K, N, Na), and 3) Develop prescriptive information from this system in conjunction with other sensor data. Most of the technical objectives for first part of the project have been achieved. A pH sensing system has been developed and initial commercialization is underway; termed the Veris Mobile Sensor Platform (MSP). The Veris Mobile Sensor Platform is tractor or pickup powered. It is designed to operate in a variety of field conditions, including no-till and conventional tillage, on bedded fields, and in vineyards. Advancements made in the area of improved data accuracy fall into two categories: 1) improved soil-electrode junction, and 2) improved data processing. Improved soil-electrode junction: Field trials and subsequent discussions with electrode vendors have led to the adoption of a double-junction reference electrode. Extensive testing in low CEC soils established the need for purified water. Improvements in soil-to-electrode contact have been made with the addition of two new components to the system. Improved data processing is provided by variable log times, which is part of new firmware that allows the unit to automatically cycle to collect another sample as soon as 4 successive readings have settled to within .02 pH of each other. Extraction routine reviews the logged pH data and selects data that meet certain quality criteria. A major objective of the project is to reduce the per-acre operating cost. Since the single largest operating expense are the pH electrodes, most of the efforts have concentrated on this component. A portion of the travel budget has been spent visiting current and prospective electrode vendors. This has resulted in a securing a new vendor who produces a lower cost pH electrode, which appears to have improved measurement life as well. With the addition of a sand guard, operating life in abrasive soils have been increased significantly. A significant obstacle has been encountered with the second set of objectives, namely the fragility of K and N ion-selective electrodes. While the pH electrode is glass and can withstand a certain amount of abrasive soils, the K and N electrodes are constructed of PVC membranes. As a result, their wear characteristics for direct soil measurements are unacceptable in a commercial application. An alternative sampler system design, which puts soil into a slurry condition, has been prototyped. This appears promising and will be a focus of the balance of the Phase II project. The third set of objectives deals with using additional sensors and geo-statistical techniques to derive prescriptive information from the ion-selective electrodes. The main focus of this effort has centered around using soil EC and near-infrared spectroscopy (NIRS) data to improve prediction of lime rec. To date, five fields have been mapped with pH electrodes along with EC and NIRS sensors, and various data analysis techniques are being used to fuse the data.

Impacts
In the United States, there are approximately 135,000,000 acres of low pH soils. These soils are primarily located in the eastern half of the United States. Worldwide, 45% of all arable land suffers from low pH. While there are a significant number of low pH fields that need pH measurements, only a percentage of these fields are actually tested. All current methods of soil sampling estimate the soil pH at un-sampled locations, either by averaging the composited values or by interpolating the values of individual samples. The density of the data collected by the Soil Sampling System reduces the error associated with these sampling methods. In field tests conducted under Phase 2, the spatial variability of soil pH and other properties has been evident. Improvements in lime application accuracy have averaged 700 lbs/acre by using the automated sampling device, versus currently available sampling practices. This improved accuracy will allow growers to improve lime applications on fields currently sampled, and encourage additional sampling on fields currently not sampled.

Publications

  • MANAGING pH VARIABILITY WITH ON-THE-GO pH MAPPING E. D. Lund, K. L. Collings, P. E. Drummond,C. D. Christy, and V. I. Adamchuk Proceedings of 7th International Conference on Precision Agriculture, Minneapolis MN (2004)
  • (IN REVIEW) Computers in Agriculture 2005 Direct measurement of soil chemical properties on-the-go using ion selective electrodes V.I. Adamchuk, E. Lund, B. Sethuramasamyraja, M.T. Morgan, A. Dobermann
  • Proceedings of the 5th European Conference on Precision Agriculture 2005 Development of soil pH and lime requirement maps using on-the-go soil sensors E.D. Lund, V.I. Adamchuk, K.L. Collings, P.E. Drummond and C.D. Christy